A novel MoS2/C nanocomposite as an anode material for lithium-ion batteries

被引:20
作者
Liu, Yan [1 ,2 ]
Tang, Daoping [1 ]
Zhong, Haoxiang [1 ]
Zhang, Qianyu [1 ]
Yang, Jianwen [3 ]
Zhang, Lingzhi [1 ]
机构
[1] Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangdong Key Lab New & Renewable Energy Res & De, 2 Nengyuan Rd, Guangzhou 510640, Guangdong, Peoples R China
[2] Univ Chinese Acad Sci, 19 A Yu Quan Rd, Beijing 100049, Peoples R China
[3] Guilin Univ Technol, Coll Chem & Bioengn, 12 Jiangan Rd, Guilin 541004, Guangxi, Peoples R China
基金
中国国家自然科学基金;
关键词
MoS2/C composite; Pluronic; Dispersing agent; Nanocomposite; Lithium-ion batteries; ORDERED MESOPOROUS MOS2; MOLYBDENUM-DISULFIDE; STORAGE PERFORMANCE; FACILE SYNTHESIS; HYDROTHERMAL SYNTHESIS; NANOSHEETS; COMPOSITE; CAPACITY; CATHODE; GROWTH;
D O I
10.1016/j.jallcom.2017.09.201
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel molybdenum disulfide/carbon (MoS2/C) nanocomposite is synthesized by a simple hydrothermal method using glucose as a carbon source and Pluronic F127 as promoting agent in presence of MoS2 nanoparticles and followed by carbonization. Pluronic F127 is used as an essential agent which inhibits the spontaneous formation of carbon microspheres during the hydrothermal reaction. The composite electrode exhibits excellent cycling stability and rate capability, delivering a reversible capacity of 882.6 mA h g(-1) at a current density of 50 mA g(-1) and a capacity retention of 82.8% after 100 cycles at a current density of 100 mA g(-1). At a higher current density of 300/500 mA g(-1), it still retains a capacity of 603.6/461.6 mA h g(-1) respectively, as compared to 295.6/228.4 mA h g(-1) for the pristine MoS2 electrode. The composite shows favorable electrochemical kinetics compared with pristine MoS2 due to the incorporation of homogenous conductive carbon layer and its nanostructured morphology. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:583 / 589
页数:7
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