Metathesis Reactions of Carbohydrates: Recent Highlights in Alkyne Metathesis

被引：26

作者：

Cristobal Lopez, J. ^{[1
]}

Plumet, Joaqun ^{[2
]}

机构：

[1] CSIC, Inst Quim Organ Gen, E-28006 Madrid, Spain

[2] Univ Complutense, Fac Quim, Dept Quim Organ, E-28040 Madrid, Spain

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 2011卷 / 10期

关键词：

Alkynes; Alkenes; Metathesis; Carbohydrates; Glycoconjugates; RING-CLOSING METATHESIS; DIVERSITY-ORIENTED SYNTHESIS; LOCKED NUCLEIC-ACID; DIELS-ALDER CYCLOADDITIONS; FUSED POLYCYCLIC ETHERS; CONCISE TOTAL-SYNTHESIS; FORMAL TOTAL-SYNTHESIS; PI-FACIAL SELECTIVITY; IN-SITU ACTIVATION; OLEFIN METATHESIS;

D O I：

10.1002/ejoc.201001518

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Metathesis processes play a prominent role in the development of useful synthetic transformations because of their mildness and tolerance of functional groups. On the other hand, carbohydrates have gained well-deserved importance in the study of biological processes. This review summarizes a decade of research in the application of alkyne metathesis (AM) reactions in some of its variants to carbohydrates and carbohydrate-related compounds.

引用

页码：1803 / 1825

页数：23

共 342 条

[1] Analogues of a locked nucleic acid with three-carbon 2′,4′-linkages:: Synthesis by ring-closing metathesis and influence on nucleic acid duplex stability and structure [J].