Thermal properties of LiF-BeF2 and LiF-BeF2-UF4 systems as applied to molten salt reactor technologies

被引：7
|
作者：
Il'ina, E. [1 ]
Mushnikov, P. [1 ]
Pershina, S. [1 ]
Rudenko, A. [1 ]
Redkin, A. [1 ]
Zaikov, Yu [1 ]
Kholkina, A. [1 ]
Voronin, V. [2 ]
机构：
[1] Russian Acad Sci, Inst High Temp Electrochem, Ural Branch, Akad Skaya St 20, Ekaterinburg 620137, Russia
[2] Russian Acad Sci, MN Mikheev Inst Met Phys, Ural Branch, S Kovalevskaya St 18, Ekaterinburg 620108, Russia
来源：
JOURNAL OF MOLECULAR LIQUIDS | 2021年 / 344卷
关键词：
Molten salt reactor; Salt fluoride mixtures; Phase transition; Peritectic compound; FUEL-CYCLE; THERMODYNAMIC ASSESSMENT; CERIUM TRIFLUORIDE; CRYSTAL-STRUCTURE; PHASE-EQUILIBRIA; VISCOSITY; FLUORIDE; LITHIUM; NUCLEAR; REFINEMENT;
D O I：
10.1016/j.molliq.2021.117731
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The thermal properties of 2LiF-BeF2 and LiF-BeF2-UF4 systems currently under active development for use in molten salt reactor designs, in various countries are studied. In order to establish liquidus and solidus temperatures of these systems, the Differential Scanning Calorimetry (DSC) method at a constant heating (cooling) rate was used. A distinction between results obtained in heating and cooling mode is identified on the basis of the much lower solidus peaks observed on cooling curves than on heating ones. This can be explained in terms of peculiarities of LiF-BeF2 peritectic compositions. The rate of cooling is much higher than the peritectic reaction rate. (C) 2021 Elsevier B.V. All rights reserved.
引用
收藏
页数：7
相关论文
共 50 条
  • [1] Thermophysical Properties of Several Molten Mixtures of the LiF-BeF2-UF4 System
    Bobrova, K. O.
    Dokutovich, V. N.
    Mushnikov, P. N.
    RUSSIAN METALLURGY, 2023, 2023 (02): : 126 - 135
  • [2] Fuel Cycle of the LiF-BeF2 Molten Salt Actinide Burner Reactor
    Zakirov, R. Ya.
    Ignatiev, V. V.
    PHYSICS OF ATOMIC NUCLEI, 2023, 86 (08) : 1894 - 1901
  • [3] TRITIUM RECOVERY FROM MOLTEN LIF-BEF2 SALT
    OISHI, J
    MORIYAMA, H
    MAEDA, S
    ASAOKA, Y
    FUSION ENGINEERING AND DESIGN, 1989, 8 : 317 - 321
  • [4] A miscibility gap in LiF-BeF2 and LiF-BeF2-ThF4
    van der Meer, JPM
    Konings, RJM
    Jacobs, MHG
    Oonk, HAJ
    JOURNAL OF NUCLEAR MATERIALS, 2005, 344 (1-3) : 94 - 99
  • [5] Thermal neutron scattering data for liquid molten salt LiF-BeF2
    Wang, Jia
    Song, Hongzhou
    Bai, Yun
    Sun, Weili
    ND 2019: INTERNATIONAL CONFERENCE ON NUCLEAR DATA FOR SCIENCE AND TECHNOLOGY, 2020, 239
  • [6] Density Measurements of Molten LiF-BeF2 and LiF-BeF2-LaF3 Salt Mixtures by Neutron Radiography
    Moon, Jisue
    McFarlane, Joanna
    Andrews, Hunter B.
    Robb, Kevin R.
    Ross, Molly
    Sulejmanovic, Dino
    Zhang, Yuxuan
    Stringfellow, Erik
    Agca, Can
    Schorne-Pinto, Juliano
    Besmann, Theodore M.
    ACS OMEGA, 2024, 9 (25): : 27204 - 27213
  • [7] Density and heat capacity of some molten mixtures in system LiF-BeF2-UF4
    Redkin, A.
    Khudorozhkova, A.
    Il'ina, E.
    Pershina, S.
    Mushnikov, P.
    Isakov, A.
    Zaikov, Yu
    Kataev, A.
    Laptev, M.
    JOURNAL OF MOLECULAR LIQUIDS, 2021, 341
  • [8] PHASE EQUILIBRIA IN THE TERNARY FUSED-SALT SYSTEM LIF-BEF2-UF4
    JONES, LV
    ETTER, DE
    HUDGENS, CR
    HUFFMAN, AA
    RHINEHAMMER, TB
    ROGERS, NE
    TUCKER, PA
    WITTENBERG, LJ
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1962, 45 (02) : 79 - 83
  • [9] Molecular dynamics investigation on microstructure and diffusion properties of LiF-BeF2 molten salt
    He G.
    Tang R.
    Duan X.
    Xie L.
    Fu J.
    Dai J.
    Qian Y.
    Wang J.
    Huagong Xuebao/CIESC Journal, 2020, 71 (08): : 3565 - 3574
  • [10] CHARACTERISTIC DIFFUSION PHENOMENA OF FLUORINE IN MOLTEN LIF-BEF2 AND NAF-BEF2 SYSTEMS
    OHNO, H
    FURUKAWA, K
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1983, 130 (03) : C126 - C126
12345