Catalytic hydroalkoxylation of alkenes by iron(III) catalyst

被引：24

作者：

Ke, Fang ^{[1
]}

Li, Zhengkai ^{[1
]}

Xiang, Haifeng ^{[1
]}

Zhou, Xiangge ^{[1
]}

机构：

[1] Sichuan Univ, Inst Homogeneous Catalysis, Coll Chem, Chengdu 610064, Peoples R China

来源：

TETRAHEDRON LETTERS | 2011年 / 52卷 / 02期

关键词：

Alcohol; Alkene; Hydroalkoxylation; Iron; INTRAMOLECULAR HYDROALKOXYLATION; SOLVOMERCURATION-DEMERCURATION; EFFICIENT CATALYST; CARBOXYLIC-ACIDS; ALCOHOL SOLVENTS; OLEFINS; HYDROAMINATION; FUNCTIONALIZATION; TRIFLUOROACETATE; BONDS;

D O I：

10.1016/j.tetlet.2010.11.036

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Catalytic hydroalkoxylation of alkenes by iron(III) chloride in the presence of toluenesulfonic acid (TsOH) was developed in moderate to good yields up to 91%. Intramolecular cyclization of 5-hydroxyl pentene afforded 2-methyltetrahedronfuran in 63% yield. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：318 / 320

页数：3

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