Fluorescence line narrowing spectroscopy of Eu3+ in zinc-thallium-tellurite glass

被引：17
作者：
Tuyen, V. P. [1 ]
Hayakawa, T. [1 ,2 ,3 ]
Nogami, M. [1 ]
Duclere, J. R. [2 ]
Thomas, P. [2 ]
机构：
[1] Nagoya Inst Technol, Dept Frontier Mat, Fields Adv Energy Convers, Showa Ku, Nagoya, Aichi 466855, Japan
[2] Univ Limoges, Fac Sci, CNRS, UMR 6638, F-87060 Limoges, France
[3] Toyota Phys & Chem Res Inst, Aichi 4801192, Japan
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2010年 / 183卷 / 11期
关键词：
Tellurite glass; Europium; Crystal field parameters; Fluorescence line narrowing; Asymmetry; RARE-EARTH IONS; OXIDE GLASSES; 2ND-HARMONIC GENERATION; OPTICAL SPECTROSCOPY; SITE; EUROPIUM(III); INTENSITIES; ABSORPTION; SPECTRA; BORATE;
D O I：
10.1016/j.jssc.2010.08.025
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The environment of Eu3+ in zinc-thallium-tellurite glass of the molar composition 60TeO(2)-30TIO(05)-9.9ZnO-0.1Eu(2)O(3) was investigated by laser-induced fluorescence line narrowing (FLN) techniques using Eu3+ as a local site probe. From the site selective luminescence spectra of Eu3+ at 7 K, the energies of the Stark components of the F-7(1) and F-7(2) states were recorded and then the crystal field parameters B-nm were calculated assuming a C-2v site symmetry. The ratios B-22/B-20 and B-44/B-40 for each excitation energy within F-7(0)-D-5(0) transition were obtained and compared with the values calculated for Eu3+ in other types of glasses. (C) 2010 Elsevier Inc. All rights reserved.
引用
收藏
页码：2714 / 2719
页数：6
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