Ultrafast liquid water transport through graphene-based nanochannels measured by isotope labelling

被引:68
作者
Sun, Pengzhan [1 ]
Liu, He [2 ]
Wang, Kunlin [1 ]
Zhong, Minlin [1 ]
Wu, Dehai [2 ]
Zhu, Hongwei [1 ,3 ]
机构
[1] Tsinghua Univ, Sch Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China
[2] Tsinghua Univ, Dept Mech Engn, Beijing 100084, Peoples R China
[3] Tsinghua Univ, Ctr Nano & Micro Mech, Beijing 100084, Peoples R China
关键词
OXIDE MEMBRANES; CARBON NANOTUBES; PERMEATION; SEPARATION; ULTRATHIN; FLOW;
D O I
10.1039/c4cc10103k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Based on isotope labelling, we found that liquid water can afford an ultrafast permeation through graphene-based nanochannels with a diffusion coefficient 4-5 orders of magnitude greater than in the bulk case. When dissolving ions in sources, the diffusion coefficient of ions through graphene channels lies in the same order of magnitude as water, while the ion diffusion is slightly faster than water, indicating that the ions are mainly transported by water flows and the delicate interactions between ions and nanocapillary walls also take effect in the accelerated ion transportation.
引用
收藏
页码:3251 / 3254
页数:4
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