STM investigation of specific anion adsorption on Cu(111) in sulfuric acid electrolyte

被引:62
作者
Wilms, M [1 ]
Broekmann, P [1 ]
Kruft, M [1 ]
Park, Z [1 ]
Stuhlmann, C [1 ]
Wandelt, K [1 ]
机构
[1] Univ Bonn, Inst Phys & Theoret Chem, D-53115 Bonn, Germany
关键词
adsorption; copper; electrochemical methods; low index single crystal surfaces; metal-electrolyte interfaces; scanning tunneling microscopy; surface structure; sulfate;
D O I
10.1016/S0039-6028(98)00011-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The reversible specific adsorption of sulfate on Cu(111) was investigated using atomic resolution scanning tunneling microscopy (STM). Continuous change of the sample potential during a scan allowed imaging surface phase transitions. The appearance and disappearance of a sulfate adlayer forming a Moire pattern were observed. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:83 / 86
页数:4
相关论文
共 50 条
  • [41] A density-functional theory study of electrochemical adsorption of sulfuric acid anions on Pt(111)
    Santana, Juan A.
    Cabrera, Carlos R.
    Ishikawa, Yasuyuki
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2010, 12 (32) : 9526 - 9534
  • [42] The Influence of Specific Anion Adsorption on the Surface Roughness of Electrodeposited Polycrystalline Cu Films
    Vasiljevic, N.
    Wood, M.
    Heard, P. J.
    Schwarzacher, W.
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2010, 157 (04) : D193 - D198
  • [43] Interaction of sulfuric acid with dolomite (104) surface and its impact on the adsorption of oleate anion: a DFT study
    Cao, Qinbo
    Zou, Heng
    Chen, Xiumin
    Yu, Xingcai
    PHYSICOCHEMICAL PROBLEMS OF MINERAL PROCESSING, 2020, 56 (01): : 34 - 42
  • [44] IN-SITU AND EX-SITU IRAS, LEED AND EC-STM STUDIES OF UNDERPOTENTIALLY DEPOSITED COPPER ON A PT(111) ELECTRODE IN SULFURIC-ACID-SOLUTION - COADSORPTION OF SULFATE ION WITH COPPER
    SHINGAYA, Y
    MATSUMOTO, H
    OGASAWARA, H
    ITO, M
    SURFACE SCIENCE, 1995, 335 (1-3) : 23 - 31
  • [45] Ab Initio Investigation of the Adsorption and Dissociation of O2 on Cu-Skin Cu3Au(111) Surface
    Yu, Yanlin
    Liu, Zhiming
    Huang, Wenxian
    Zhou, Shan
    Hu, Zuofu
    Wang, Ligen
    CATALYSTS, 2022, 12 (11)
  • [46] In situ STM and ex situ XPS examination of the adsorption and polymerization of metanilic acid and aniline on Au(111) electrode
    Chen, Sihzih
    Yau, ShuehLin
    Fan, LiangJen
    Yang, YawWen
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2014, 716 : 150 - 157
  • [47] The effect of specific chloride adsorption on the electrochemical behavior of ultrathin Pd films deposited on Pt(111) in acid solution
    Arenz, M
    Stamenkovic, V
    Schmidt, TJ
    Wandelt, K
    Ross, PN
    Markovic, NM
    SURFACE SCIENCE, 2003, 523 (1-2) : 199 - 209
  • [48] Investigation of adsorption characteristics of methionine at mild steel/sulfuric acid interface:: An experimental and theoretical study
    Ozecan, Muzaffer
    Karadag, Faruk
    Dehri, Ilyas
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2008, 316 (1-3) : 55 - 61
  • [49] Electronic Structures of Quaterthiophene and Septithiophene on Cu(111): Spatial Distribution of Adsorption-Induced States Studied by STM and DFT Calculation
    Kakudate, Toshiyuki
    Tsukamoto, Shigeru
    Kubo, Osamu
    Nakaya, Masato
    Nakayama, Tomonobu
    JOURNAL OF PHYSICAL CHEMISTRY C, 2016, 120 (12) : 6681 - 6688
  • [50] Adsorption films based on indazole derivatives for application to protect Cu in sulfuric acid: Experimental and theoretical approaches
    Zeng, Jie
    Gan, Yue
    Xu, Zhixiong
    Zhu, Hanhong
    Tan, Bochuan
    Li, Wenpo
    JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2023, 151