Ruthenium(IV) alkylidenes as precatalysts for direct arylations of Alkenes with aryl chlorides and an application to sequential catalysis

被引：142
作者：
Ackermann, Lutz [1 ]
Born, Robert [1 ]
Alvarez-Bercedo, Paula [1 ]
机构：
[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 33期
关键词：
alkenes; C-H activation; hydrosilylation; ruthenium carbenes; sequential catalysis;
D O I：
10.1002/anie.200701727
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Jack of all trades? A ruthenium(IV) carbene complex catalyzes the diastereoselective direct arylation of alkenes using aryl chlorides with high efficiency, which sets the stage for the development of a direct arylation-hydrosilylation sequence (see scheme). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：6364 / 6367
页数：4
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