Kinetic characterization of the esterification of sulfuric acid by ethanol using capillary electrophoretic ion analysis

被引：2
作者：
Chen, L [1 ]
Johnson, BD [1 ]
Grinberg, N [1 ]
Bicker, GR [1 ]
Ellison, DK [1 ]
机构：
[1] Merck Res Labs, Rahway, NJ 07065 USA
来源：
JOURNAL OF LIQUID CHROMATOGRAPHY & RELATED TECHNOLOGIES | 1998年 / 21卷 / 09期
关键词：
D O I：
10.1080/10826079808005876
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
A capillary electrophoretic ion analysis method was developed for monitoring esterification of sulfuric acid by ethanol to form monoethylsulfate. Since the analytes of interest have no chromophores, detection was performed utilizing indirect photometric detection. Several background electrolyte systems were evaluated to optimize the efficiency of the separation. The method was more sensitive and specific ire comparison to alternative techniques. Pseudo-first-order rate constants for the esterification reaction were determined as a function of temperature and the activation energy was calculated.
引用
收藏
页码：1259 / 1272
页数：14
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