A Rothmund-Kornfeld model of Cs+-K+-Na+ exchange on spherical resorcinol-formaldehyde (sRF) resin in Hanford nuclear waste

被引：5

作者：

Reynolds, Jacob G. ^{[1
]}

Tardiff, Benjamin M. ^{[2
]}

机构：

[1] Washington River Protect Solut LLC, POB 850, Richland, WA 99354 USA

[2] AEM Consulting LLC, Richland, WA 99354 USA

来源：

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY | 2016年 / 309卷 / 02期

关键词：

Ion exchange; Cation exchange; Resorcinol-formaldehyde; Rothumnd-Kornfeld; Hanford; Cesium; ION-EXCHANGE; CATION-EXCHANGE; CESIUM REMOVAL; TERNARY EXCHANGE; SELECTIVITY; BINARY; EQUILIBRIUM; ADSORPTION; SOILS;

D O I：

10.1007/s10967-015-4660-x

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The Hanford site, near Richland, WA, in the U.S.A., has more than 55 million gallons of high-level nuclear waste, much of which is high-ionic strength sodium and potassium containing electrolyte solutions. Spherical-resorcinol formaldehyde ion exchange resin is being developed to remove radioactive cesium from the waste. This study develops a model in the Rothmund-Kornfeld framework to predict Cs+-K+-Na+ selectivity on the resin. The model is found to fit the available data well, with an R (2) of greater than 0.985. The Rothmund-Kornfeld model is thus recommended for use in modelling ternary ion-exchange in Hanford waste.

引用

页码：813 / 818

页数：6

共 2 条

[1] A Rothmund–Kornfeld model of Cs+–K+–Na+ exchange on spherical resorcinol-formaldehyde (sRF) resin in Hanford nuclear waste
Jacob G. Reynolds
Benjamin M. Tardiff
Journal of Radioanalytical and Nuclear Chemistry, 2016, 309 : 813 - 818
[2] Spherical resorcinol-formaldehyde resin testing for cesium removal from Hanford tank waste simulant
Fiskum, S. K.
Blanchard, D. L.
Steele, M. J.
Thomas, K. K.
Trang-Le, T.
Thorson, M. R.
SEPARATION SCIENCE AND TECHNOLOGY, 2006, 41 (11) : 2461 - 2474

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