Nanocrystalline Cellulose Supported MnO2 Composite Materials for High-Performance Lithium-Ion Batteries

被引：9
作者：
Tran, Quang Nhat [1 ]
Vo, Thuan Ngoc [1 ]
Kim, Il Tae [1 ]
Kim, Ji Hyeon [1 ]
Lee, Dal Ho [2 ]
Park, Sang Joon [1 ]
机构：
[1] Gachon Univ, Dept Chem & Biol Engn, Seongnam 13120, Gyeonggi Do, South Korea
[2] Gachon Univ, Dept Elect Engn, Seongnam 13120, Gyeonggi Do, South Korea
来源：
MATERIALS | 2021年 / 14卷 / 21期
关键词：
manganese dioxide; nanocrystalline cellulose; lithium-ion batteries; nanocomposite; discharge capacity; REDUCED GRAPHENE OXIDE; ANODE MATERIALS; NEGATIVE-ELECTRODE; GENERAL-SYNTHESIS; FACILE SYNTHESIS; BINDER-FREE; NANOTUBES; HYBRID; MN3O4; NANOPARTICLES;
D O I：
10.3390/ma14216619
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The rate capability and poor cycling stability of lithium-ion batteries (LIBs) are predominantly caused by the large volume expansion upon cycling and poor electrical conductivity of manganese dioxide (MnO2), which also exhibits the highest theoretical capacity among manganese oxides. In this study, a nanocomposite of nanosized MnO2 and pyrolyzed nanocrystalline cellulose (CNC) was prepared with high electrical conductivity to enhance the electrochemical performance of LIBs. The nanocomposite electrode showed an initial discharge capacity of 1302 mAh g(-1) at 100 mA g(-1) and exhibited a high discharge capacity of 305 mAh g(-1) after 1000 cycles. Moreover, the MnO2-CNC nanocomposite delivered a good rate capability of up to 10 A g(-1) and accommodated the large volume change upon repeated cycling tests.
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页数：12
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[1]   Nanostructured materials for advanced energy conversion and storage devices [J].
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