Visible-light-induced, UiO-67-Ru-catalyzed oxidative cross-coupling for constructing β-acetylamino acrylosulfones

被引：8
作者：
Xu, Siyan [1 ,2 ]
Kong, Hao [1 ,2 ]
Zhang, Ronghua [1 ,2 ]
机构：
[1] Tongji Univ, Sch Chem Sci & Engn, 1239 Siping Rd, Shanghai 200092, Peoples R China
[2] Tongji Univ, Shanghai Key Lab Chem Assessment & Sustainabil, 1239 Siping Rd, Shanghai 200092, Peoples R China
来源：
TETRAHEDRON LETTERS | 2020年 / 61卷 / 11-12期
基金：
中国国家自然科学基金;
关键词：
beta-Acetylamino acrylosulfones; Photoredox; MOFs-catalyst; C-S coupling; METAL-ORGANIC FRAMEWORKS; PHOTOCATALYTIC CO2 REDUCTION; HIGHLY EFFICIENT APPROACH; SULFINIC ACIDS; STEREOSELECTIVE-SYNTHESIS; C-C; ENAMIDES; SULFONES; ALKENES; DIFUNCTIONALIZATION;
D O I：
10.1016/j.tetlet.2020.151629
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel approach to generate beta-acetylamino acrylosulfones using the photocatalyst UiO-67-Ru under visible light has been developed. The entire reaction is applicable to sulfone-containing skeleton and exhibits good substrate scope. UiO-67-Ru-catalyzed protocol provides a sustainable and efficient access to construct a variety of sulfones via the direct functionalization of C-H bonds. (C) 2020 Elsevier Ltd. All rights reserved.
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页数：6
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