Visible-light-induced, UiO-67-Ru-catalyzed oxidative cross-coupling for constructing β-acetylamino acrylosulfones

被引：7

作者：

Xu, Siyan ^{[1
,2
]}

Kong, Hao ^{[1
,2
]}

Zhang, Ronghua ^{[1
,2
]}

机构：

[1] Tongji Univ, Sch Chem Sci & Engn, 1239 Siping Rd, Shanghai 200092, Peoples R China

[2] Tongji Univ, Shanghai Key Lab Chem Assessment & Sustainabil, 1239 Siping Rd, Shanghai 200092, Peoples R China

来源：

TETRAHEDRON LETTERS | 2020年 / 61卷 / 11-12期

基金：

中国国家自然科学基金;

关键词：

beta-Acetylamino acrylosulfones; Photoredox; MOFs-catalyst; C-S coupling; METAL-ORGANIC FRAMEWORKS; PHOTOCATALYTIC CO2 REDUCTION; HIGHLY EFFICIENT APPROACH; SULFINIC ACIDS; STEREOSELECTIVE-SYNTHESIS; C-C; ENAMIDES; SULFONES; ALKENES; DIFUNCTIONALIZATION;

D O I：

10.1016/j.tetlet.2020.151629

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel approach to generate beta-acetylamino acrylosulfones using the photocatalyst UiO-67-Ru under visible light has been developed. The entire reaction is applicable to sulfone-containing skeleton and exhibits good substrate scope. UiO-67-Ru-catalyzed protocol provides a sustainable and efficient access to construct a variety of sulfones via the direct functionalization of C-H bonds. (C) 2020 Elsevier Ltd. All rights reserved.

引用

页数：6

共 18 条

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