Core-functionalized nanoaggregates: preparation via polymerization-induced self-assembly and their applications

被引：9

作者：

Damsongsang, Panittha ^{[1
]}

Hoven, Voravee P. ^{[1
,2
]}

Yusa, Shin-ichi ^{[3
]}

机构：

[1] Chulalongkorn Univ, Fac Sci, Dept Chem, Bangkok 10330, Thailand

[2] Chulalongkorn Univ, Ctr Excellence Mat & Biointerfaces, Bangkok 10330, Thailand

[3] Univ Hyogo, Grad Sch Engn, Dept Appl Chem, 2167 Shosha, Himeji, Hyogo 6572280, Japan

来源：

NEW JOURNAL OF CHEMISTRY | 2021年 / 45卷 / 29期

基金：

日本学术振兴会;

关键词：

CONTROLLED/LIVING RADICAL POLYMERIZATION; AQUEOUS DISPERSION POLYMERIZATION; BLOCK-COPOLYMER MICELLES; DRUG-DELIVERY; RAFT POLYMERIZATION; POSTPOLYMERIZATION MODIFICATION; RESPONSIVE NANOPARTICLES; EMULSION POLYMERIZATION; TRIBLOCK COPOLYMERS; CLICK CHEMISTRY;

D O I：

10.1039/d1nj01791h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The combination of polymerization-induced self-assembly (PISA) and post-polymerization modification is a versatile route to prepare core-functionalized nanoaggregates. PISA is a useful approach for preparing in situ self-assembled nano-objects, in which morphological nanostructures are tunable with a high solid concentration that can afford scale-up syntheses. Herein, the preparation via PISA of diblock copolymers that have functional groups in their structures to be further post-functionalized using active modifiers has been reviewed. The resulting multifunctional nanoaggregates exhibit great potential for use in a wide range of applications, for example, crosslinked nano-objects having improved stability, stimuli responsive vehicles for drug delivery, and fluorescent nanomaterials for bioimaging.

引用

页码：12776 / 12791

页数：16

共 121 条

[1] An emerging post-polymerization modification technique: The promise of thiol-para-fluoro click reaction [J].

Agar, Soykan ;

Baysak, Elif ;

Hizal, Gurkan ;

Tunca, Umit ;

Durmaz, Hakan .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2018, 56 (12) :1181-1198

[2] Vesicles and liposomes:: A self-assembly principle beyond lipids [J].

Antonietti, M ;

Förster, S .

ADVANCED MATERIALS, 2003, 15 (16) :1323-1333

[3] Utilizing click chemistry to design functional interfaces through post-polymerization modification [J].

Arnold, Rachelle M. ;

Huddleston, N. Eric ;

Locklin, Jason .

JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (37) :19357-19365

[4] Permeable Protein-Loaded Polymersome Cascade Nanoreactors by Polymerization-Induced Self-Assembly [J].

Blackman, Lewis D. ;

Varlas, Spyridon ;

Arno, Maria C. ;

Fayter, Alice ;

Gibson, Matthew I. ;

O'Reilly, Rachel K. .

ACS MACRO LETTERS, 2017, 6 (11) :1263-1267

[5] Predictive Phase Diagrams for RAFT Aqueous Dispersion Polymerization: Effect of Block Copolymer Composition, Molecular Weight, and Copolymer Concentration [J].

Blanazs, A. ;

Ryan, A. J. ;

Armes, S. P. .

MACROMOLECULES, 2012, 45 (12) :5099-5107

[6] Self-Assembled Block Copolymer Aggregates: From Micelles to Vesicles and their Biological Applications [J].

Blanazs, Adam ;

Armes, Steven P. ;

Ryan, Anthony J. .

MACROMOLECULAR RAPID COMMUNICATIONS, 2009, 30 (4-5) :267-277

[7] Post-polymerization functionalization of polyolefins [J].

Boaen, NK ;

Hillmyer, MA .

CHEMICAL SOCIETY REVIEWS, 2005, 34 (03) :267-275

[8] Controlled/living radical polymerization: Features, developments, and perspectives [J].

Braunecker, Wade A. ;

Matyjaszewski, Krzysztof .

PROGRESS IN POLYMER SCIENCE, 2007, 32 (01) :93-146

[9] Sphere-to-worm morphological transitions and size changes through thiol-para-fluoro core modification of PISA-made nano-objects [J].

Busatto, Nicolas ;

Keddie, Joseph L. ;

Roth, Peter J. .

POLYMER CHEMISTRY, 2020, 11 (03) :704-711

[10] Reactive Polymorphic Nanoparticles: Preparation via Polymerization-Induced Self-Assembly and Postsynthesis Thiol-para-Fluoro Core Modification [J].

Busatto, Nicolas ;

Stolojan, Vlad ;

Shaw, Michael ;

Keddie, Joseph L. ;

Roth, Peter J. .

MACROMOLECULAR RAPID COMMUNICATIONS, 2019, 40 (02)

← 1 2 3 4 5 6 7 8 9 10 →