CO2-Stable and Cobalt-Free Dual-Phase Membrane for Oxygen Separation

被引：189
作者：
Luo, Huixia [2 ]
Efimov, Konstantin [2 ]
Jiang, Heqing [2 ]
Feldhoff, Armin [2 ]
Wang, Haihui [1 ]
Caro, Juergen [2 ]
机构：
[1] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Peoples R China
[2] Leibniz Univ Hannover, Inst Phys Chem & Electrochem, D-30167 Hannover, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 03期
关键词：
carbon dioxide; membranes; oxide membranes; oxygen separation; HOLLOW-FIBER MEMBRANE; PEROVSKITE-TYPE OXIDE; COMPOSITE MEMBRANES; PERMEABLE MEMBRANE; TRANSPORT-PROPERTIES; THERMAL-DECOMPOSITION; PERMEATION PROPERTIES; FUEL COMBUSTION; REACTOR; CO2;
D O I：
10.1002/anie.201003723
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Cleaning up their act: A novel CO2-stable and cobalt-free dual-phase membrane for oxygen separation from air has been developed that consists of 40 wt % NiFe2O4 and 60 wt % Ce 0.9Gd0.1O2-δ. This membrane shows a steady oxygen permeation flux over 100 h using CO2 as sweep gas at 1000 °C. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：759 / 763
页数：5
相关论文
共 59 条
  • [1] Oxygen permeation through oxygen ionic or mixed-conducting ceramic membranes with chemical reactions
    Akin, FT
    Lin, JYS
    [J]. JOURNAL OF MEMBRANE SCIENCE, 2004, 231 (1-2) : 133 - 146
  • [2] [Anonymous], ANGEW CHEM
  • [3] Influence of CO2 on the oxygen permeation performance and the microstructure of perovskite-type (Ba0.5Sr0.5)(Co0.8Fe0.2)O3-δ membranes
    Arnold, Mirko
    Wang, Haihui
    Feldhoff, Armin
    [J]. JOURNAL OF MEMBRANE SCIENCE, 2007, 293 (1-2) : 44 - 52
  • [4] Hot spot hydrocarbon oxidation catalysed by doped perovskites - Towards cleaner diesel power
    Beckers, J
    Rothenberg, G
    [J]. CHEMPHYSCHEM, 2005, 6 (02) : 223 - 225
  • [5] Oxy-fuel combustion technology for coal-fired power generation
    Buhre, BJP
    Elliott, LK
    Sheng, CD
    Gupta, RP
    Wall, TF
    [J]. PROGRESS IN ENERGY AND COMBUSTION SCIENCE, 2005, 31 (04) : 283 - 307
  • [6] Chen C. S., 1994, THESIS U TWENTE NETH
  • [7] Conversion of methane to syngas by a membrane-based oxidation-reforming process
    Chen, CS
    Feng, SJ
    Ran, S
    Zhu, DC
    Liu, W
    Bouwmeester, HJM
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (42) : 5196 - 5198
  • [8] CHEN CS, 2003, ANGEW CHEM, V115, P5354
  • [9] Novel Cobalt-Free Oxygen-Permeable Perovskite-Type Membrane
    Efimov, Konstantin
    Halfer, Torben
    Kuhn, Alexander
    Heitjans, Paul
    Caro, Juergen
    Feldhoff, Armin
    [J]. CHEMISTRY OF MATERIALS, 2010, 22 (04) : 1540 - 1544
  • [10] Crystalline Intermediate Phases in the Sol-Gel-Based Synthesis of La2NiO4+δ
    Efimov, Konstantin
    Arnold, Mirko
    Martynczuk, Julia
    Feldhoff, Armin
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2009, 92 (04) : 876 - 880
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