Design and Synthesis of Multipurpose Derivatives for N-Hydroxyimide and NHPI-based Catalysis Applications**

被引：13

作者：

Caruso, Manfredi ^{[1
]}

Petroselli, Manuel ^{[2
]}

Cametti, Massimo ^{[1
]}

机构：

[1] Politecn Milan, Dipartimento Chim Mat & Ingn Chim Giulio Natta, Via Luigi Mancinelli 7, I-20131 Milan, Italy

[2] Swiss Fed Inst Technol, Lab Organ Chem, Vladimir Prelog Weg 3, CH-8093 Zurich, Switzerland

来源：

CHEMISTRYSELECT | 2021年 / 6卷 / 45期

关键词：

bond dissociation energy; cyclization reaction; ionic liquids; N-hydroxylphthalimide (NHPI); zeolitic imidazolate frameworks (ZIF); METAL-ORGANIC FRAMEWORKS; AEROBIC OXIDATION; HYDROXYPHTHALIMIDE NHPI; SOLVENT-FREE; IONIC LIQUIDS; PHASE; ACCELERATION; REACTIVITY; ALCOHOLS; BEARING;

D O I：

10.1002/slct.202103792

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bi- and tricyclic derivatives 1 a and 2 a (Scheme 2) combining the catalytic N-hydroxyimide NO-H unit with the imidazole moiety were designed as multipurpose derivatives and proposed as chemical tools for achieving improved homogeneous and heterogeneous aerobic oxidation catalysis. BDE tunability, formation of a ZIF and of imidazolium ionic-liquid-like materials were obtained for N-hydroxyphthalimide (NHPI)-based 2 a and here described.

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页码：12975 / 12980

页数：6

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