Controllable Fabrication of Porous ZnO Nanofibers by Electrospun with Enhanced Acetone Sensing Property

被引：10

作者：

Chen, Xiang ^{[1
]}

Gao, Qian ^{[2
]}

Xiang, Di ^{[1
]}

Lin, Huiming ^{[1
]}

Han, Xiao ^{[1
]}

Li, Xin ^{[1
]}

Du, Shantao ^{[1
]}

Qu, Fengyu ^{[1
]}

机构：

[1] Harbin Normal Univ, Coll Chem & Chem Engn, Harbin 150025, Peoples R China

[2] Jilin Univ, Coll Mat Sci & Engn, Changchun 130022, Peoples R China

来源：

SCIENCE OF ADVANCED MATERIALS | 2015年 / 7卷 / 03期

基金：

中国国家自然科学基金; 黑龙江省自然科学基金;

关键词：

ZnO; Porous Nanofibers; Electospun; Acetone Sensor; GAS; SENSITIVITY; NANOWIRES; NANORODS; FIBER;

D O I：

10.1166/sam.2015.2031

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Porous ZnO nanofibers were prepared through the electrospun method using zinc acetate as zinc source and polyvinylpyrrolidone as thickener agent. Under adjusting the amount of zinc acetate, the synthesized porous ZnO nanofibers show various structures (fiber, tube, and fiber-in-tube). And the formation mechanism was discussed in detail. These porous ZnO samples show the uniform structure about 200 to 300 nm in diameter and several microns in length. All the fibers are composed of many ZnO nanoparticles (20-30 nm) that assemble to form the porous structure and induce the large surface area and high pore volume of the sample. These porous ZnO nanofibers were configured as high performance sensors for acetone sensing, showing high sensitivity (S=243.3 at 500 ppm), low detection limit (10 ppm), fast response/ recovery (7/17 s), and very good selectivity.

引用

页码：526 / 531

页数：6

共 29 条

[1] Ethylene glycol assisted hydrothermal synthesis of flower like ZnO architectures [J].

Ashoka, S. ;

Nagaraju, G. ;

Tharamani, C. N. ;

Chandrappa, G. T. .

MATERIALS LETTERS, 2009, 63 (11) :873-876

[2] Cationic and Anionic Surface Binding Sites on Nanocrystalline Zinc Oxide: Surface Influence on Photoluminescence and Photocatalysis [J].

Bohle, D. Scott ;

Spina, Carla J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (12) :4397-4404

[3] Fabrication and Characterization of ZnO Single Nanowire-Based Hydrogen Sensor [J].

Das, Sachindra Nath ;

Kar, Jyoti Prakash ;

Choi, Ji-Hyuk ;

Lee, Tae Il ;

Moon, Kyeong-Ju ;

Myoung, Jae-Min .

JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (03) :1689-1693

[4] Fabrication of zeolite hollow fibers by coaxial electrospinning [J].

Di, Jiancheng ;

Chen, Hongyan ;

Wang, Xiaofang ;

Zhao, Yong ;

Jiang, Lei ;

Yu, Jihong ;

Xu, Ruren .

CHEMISTRY OF MATERIALS, 2008, 20 (11) :3543-3545

[5] On the sensitivity of conductimetric acetone gas sensor based on polypyrrole and polyaniline conducting polymers [J].

Do, Jing-Shan ;

Wang, Shi-Hong .

SENSORS AND ACTUATORS B-CHEMICAL, 2013, 185 :39-46

[6] Hybrid structure of zinc oxide nanorods and three dimensional graphene foam for supercapacitor and electrochemical sensor applications [J].

Dong, Xiaochen ;

Cao, Yunfa ;

Wang, Jing ;

Chan-Park, Mary B. ;

Wang, Lianhui ;

Huang, Wei ;

Chen, Peng .

RSC ADVANCES, 2012, 2 (10) :4364-4369

[7] ZnO nanowire transistors [J].

Goldberger, J ;

Sirbuly, DJ ;

Law, M ;

Yang, P .

JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (01) :9-14

[8]

Kind H, 2002, ADV MATER, V14, P158, DOI 10.1002/1521-4095(20020116)14:2<158::AID-ADMA158>3.0.CO

[9]

2-W

[10] Chemical sensing and catalysis by one-dimensional metal-oxide nanostructures [J].

Kolmakov, A ;

Moskovits, M .

ANNUAL REVIEW OF MATERIALS RESEARCH, 2004, 34 :151-180

← 1 2 3 →