A Square-Planar Ruthenium(II) Complex with a Low-Spin Configuration

被引：58

作者：

Askevold, Bjorn ^{[1
]}

Khusniyarov, Marat M. ^{[2
]}

Herdtweck, Eberhardt ^{[1
]}

Meyer, Karsten ^{[2
]}

Schneider, Sven ^{[1
]}

机构：

[1] Tech Univ Munich, Dept Chem, D-85748 Garching, Germany

[2] Univ Erlangen Nurnberg, Dept Chem & Pharm, D-91058 Erlangen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 41期

关键词：

amido ligands; beta-hydrogen elimination; pincer complexes; ruthenium; spin multiplicity; LIGANDS SYNTHESIS; HYDROGENATION; REACTIVITY; CARBENE; STATE; DEHYDROGENATION; 4-COORDINATE; EQUILIBRIUM; MECHANISM; KETONES;

D O I：

10.1002/anie.201002296

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ground-about: The ruthenium(II) complex [RuCl{N(CH2CH 2PtBu2)2}] (B) is obtained in high yield by the reaction of [RuCl2{HN(CH2CH2PtBu 2)2}] (A) with KOtBu. Complex B exhibits an unusual electronic low-spin (S=0) ground-state configuration. Comparison with Caulton's [RuCl{N(SiMe2CH2PtBu2)2}] (ground state: S=1) shows that the ground-state spin multiplicity in these complexes is controlled by the N→Ru π-donor strength. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7566 / 7569

页数：4

共 50 条

[21] ESR AND OPTICAL-SPECTRA OF LOW-SPIN SQUARE-PLANAR COBALT(II) COMPLEXES WITH SOME QUADRIDENTATE SCHIFF-BASES OF N2S2-TYPE
NISHIDA, Y
SUMITA, A
KIDA, S
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1977, 50 (03) : 759 - 760
[22] ARE OCTAHEDRAL RUTHENIUM(II/III) AND OSMIUM(II/III) COMPLEXES ALWAYS LOW-SPIN?
Srnec, Martin
Chalupsky, Jakub
Rulisek, Lubomir
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 2008, 73 (10) : 1231 - 1244
[23] SPECTROSCOPIC STUDY OF SQUARE-PLANAR COMPOUNDS OF PT(II) AND PD(II) WITH SUBSTITUTED PYRIDINES .2. SQUARE-PLANAR SKELETON VIBRATIONS
PFEFFER, M
BRAUNSTEIN, P
DEHAND, J
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1974, A-30 (02) : 341 - 355
[24] An isolable, crystalline complex of square-planar silicon(IV)
Ebner, Fabian
Greb, Lutz
CHEM, 2021, 7 (08): : 2151 - 2159
[25] Synthesis and crystal structure of a rare square-planar Co(II) complex of a hydroxyamidinate ligand
Cibian, Mihaela
Derossi, Sofia
Hanan, Garry S.
DALTON TRANSACTIONS, 2011, 40 (05) : 1038 - 1040
[26] High pressure cyanide exchange study on a square-planar tetracyanometalate complex of Pt(II)
Monlien, FJ
Abou-Hamdan, A
Helm, L
Merbach, AE
HIGH PRESSURE RESEARCH, 2000, 18 (1-6) : 319 - 324
[27] Modulating the Anticancer Activity of Square-Planar Platinum (II) Complex by Its Chelated Diphosphine
Li, Ying
Hou, Zhenguo
Xiao, Zhiyin
Lu, Chunxin
Jin, Jing
He, Yi
Jin, Jia
Suntharalingam, Kogularamanan
APPLIED ORGANOMETALLIC CHEMISTRY, 2025, 39 (02)
[28] Synthesis, characterization and crystal structure of a square-planar copper(II) Schiff base complex
Chakraborty, Jishnunil
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2017, 94 (10) : 1073 - 1077
[29] THERMAL-ISOMERIZATION OF SQUARE-PLANAR NI(II) COMPLEX IN THE SOLID-STATE
DONIA, AM
THERMOCHIMICA ACTA, 1989, 152 (02) : 335 - 339
[30] A Low-Spin Ruthenium(IV)-Oxo Complex: Does the Spin State Have an Impact on the Reactivity?
Kojima, Takahiko
Hirai, Yuichirou
Ishizuka, Tomoya
Shiota, Yoshihito
Yoshizawa, Kazunari
Ikemura, Kenichiro
Ogura, Takashi
Fukuzumi, Shunichi
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (45) : 8449 - 8453

← 1 2 3 4 5 →