Highly efficient solvent-free condensation of carboxylic acids with alcohols catalysed by zinc perchlorate hexahydrate, Zn(CIO4)2•6 H2O

被引：48
作者：
Bartoli, G
Boeglin, J
Bosco, M
Locatelli, M
Massaccesi, M
Melchiorre, P
Sambri, L
机构：
[1] Dipartimento Chim Organ A Mangini, I-40136 Bologna, Italy
[2] Univ Strasbourg 1, Strasbourg, France
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2005年 / 347卷 / 01期
关键词：
atom economy; esterification; esters; heterogeneous catalysis; solvent-free; zinc perchlorate;
D O I：
10.1002/adsc.200404171
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Zinc perchlorate hexahydrate, Zn(ClO4)(2)(.) 6 H2O, efficiently catalyses the esterification between nearly equimolar amounts of carboxylic acids and alcohols. The reaction works under solvent-free conditions at relatively low temperatures. Excellent results were obtained with a wide range of substrates.
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收藏
页码：33 / 38
页数：6
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