Thermal effects on arsenic emissions during coal combustion process

被引:20
|
作者
Zhang, Weiqiang [1 ,2 ]
Sun, Qiang [1 ,2 ,3 ]
Yang, Xiuyuan [4 ]
机构
[1] China Univ Min & Technol, Key Lab Coalbed Methane Resources & Reservoir For, Minist Educ, Xuzhou 221116, Jiangsu, Peoples R China
[2] China Univ Min & Technol, Sch Resources & Geosci, Xuzhou 221116, Jiangsu, Peoples R China
[3] Univ North Carolina Charlotte, Dept Civil & Environm Engn, Charlotte, NC 28223 USA
[4] China Geol Survey, Hydrogeol & Environm Geol Survey Ctr, Baoding 071051, Hebei, Peoples R China
关键词
Thermal effects; Emission rate; Arsenic; Coal combustion; Human health; TRACE-ELEMENTS; FLY-ASH; COCOMBUSTION; SPECIATION; FLUORINE;
D O I
10.1016/j.scitotenv.2017.08.262
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In this study, the rate of emission of arsenic during the burning process of different kinds of coal is examined in order to study the volatile characteristics of arsenic during coal combustion which have negative effects on the ecological environment and human health. The results show that the emission rate of arsenic gradually increases with increased burning temperature, with a threshold of approximately 700 degrees C to 800 degrees C in the process of temperature increase. Then, the relationships among the arsenic emission rate and combustion environment, original arsenic content, combustion time, burning temperature, air flow and amount of arsenic fixing agent are discussed, and it is found that except for the original arsenic content, the rest of the factors have a nonlinear relationship with the emission rate of arsenic. That is, up to a certain level, they all contribute to the release of arsenic, and then their impact is minimal. The original arsenic content in coal is proportional to the arsenic emission rate. Therefore, taking into consideration the nonlinear relationships between factors that affect the arsenic emission rate can reduce contamination from arsenic. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:582 / 589
页数:8
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