A Fluorinated Metal-Organic Framework for High Methane Storage at Room Temperature

被引：33
作者：
Chang, Ganggang [1 ,2 ]
Wen, Huimin [2 ]
Li, Bin [2 ]
Zhou, Wei [3 ]
Wang, Hailong [2 ]
Alfooty, Khalid [4 ]
Bao, Zongbi [1 ,2 ]
Chen, Banglin [2 ,4 ]
机构：
[1] Zhejiang Univ, Coll Chem & Biol Engn, Key Lab Biomass Chem Engn, Minist Educ, Hangzhou 310027, Zhejiang, Peoples R China
[2] Univ Texas San Antonio, Dept Chem, One UTSA Circle, San Antonio, TX 78249 USA
[3] NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA
[4] King Abdulaziz Univ, Dept Chem, Fac Sci, Jeddah 22254, Saudi Arabia
来源：
CRYSTAL GROWTH & DESIGN | 2016年 / 16卷 / 06期
基金：
中国国家自然科学基金;
关键词：
GAS-STORAGE; CARBON-DIOXIDE; PORE-SIZE; HIGH H-2; ADSORPTION; CAPACITY; CH4; HYDROGEN; SITES; CO2;
D O I：
10.1021/acs.cgd.6b00385
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A fluorinated metal-organic framework NOTT-108 with single pure-phase has been synthesized for the first tine, which has enabled us to examine the effect of the substituted fluorine atoms on the methane storage. The activated NOTT-108a shows a permanent porosity comparable to its isoreticular NOTT-101a but exhibits a higher volumetric methane storage capacity of 247 cm(3) (STP) cm(-3) and a working capacity of 186 cm(3) (STP) cm(-3) (at 298 K and 65 bar) than 237 cm(3) (STP) cm(-3) and 181 cm(3) (STP) cm(-3) of NOTT-101a, attributed to the higher polarity/dipole moment of C-F bonds compared to that of C-H bonds,for the enhanced electrostatic interaction with methane molecules.
引用
收藏
页码：3395 / 3399
页数：5
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