Heteroarene N-Oxides as Oxygen Source in Organic Reactions

被引：41
作者：
Petrosyan, Andranik [1 ]
Hauptmann, Richy [1 ]
Pospech, Jola [1 ]
机构：
[1] Univ Rostock eV, Leibniz Inst Katalyse, Albert Einstein Str 29a, D-18057 Rostock, Germany
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 2018卷 / 38期
关键词：
Heteroarenes; Oxygenation; Homogeneous catalysis; Transfer oxygenation; Epoxidation; CATALYZED ASYMMETRIC EPOXIDATION; ENANTIOSELECTIVE TOTAL-SYNTHESIS; HIGHLY EFFICIENT EPOXIDATION; ELECTRON-TRANSFER PROCESS; SITE-SELECTIVE SYNTHESIS; OXO GOLD CARBENES; RUTHENIUM PORPHYRIN; METAL-FREE; OXIDATIVE CYCLIZATION; ATOM TRANSFER;
D O I：
10.1002/ejoc.201800152
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This review summarizes the utilization of heteroarene N-oxides as oxidant in organic reactions. The specific focus lies on reactions in which pyridine N-oxides are used as oxygen source in an oxygen atom transfer fashion. The scope comprises the hydroxylation of aliphatic and aromatic C-H bonds, epoxidation as well as oxygenations of alkenes and alkynes. The latter have been extensively reviewed elsewhere and are merely discussed in a conceptual manner.
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页码：5237 / 5252
页数：16
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