Synthesis, structure and fluorescence properties of a Zn(II) coordination polymer based on 2-(hydroxymethyl)-1H-imidazole-4,5-dicarboxylate

被引：11
|
作者：
Cheng, Di [1 ]
Liu, Yan-Ju [1 ]
Cheng, Fang-Rong [1 ]
Yang, Huai-Xia [1 ]
Meng, Xiang-Ru [2 ]
机构：
[1] Henan Univ Chinese Med, Pharm Coll, Zhengzhou 450008, Henan, Peoples R China
[2] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Henan, Peoples R China
来源：
JOURNAL OF CHEMICAL RESEARCH | 2018年 / 09期
关键词：
Zn(II) polymer; 2-(hydroxymethyl)-1H-imidazole-4,5-dicarboxylic acid; crystal structure; thermogravimetric analysis; fluorescence; CARBOXYLIC-ACID; CRYSTAL; FRAMEWORKS; LIGANDS; CD(II); CHAINS;
D O I：
10.3184/174751918X15366068518341
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The coordination polymer {[Zn-3(HhmIDC)(2)(H2O)(2)]center dot 2H(2)O}(n) [H(4)hmIDC = 2-(hydroxymethyl)-1H-imidazole-4,5-dicarboxylic acid] has been synthesised and structurally characterised. In the polymer, there are two crystallographically distinct Zn(II) ions that adopt different coordination environments. The polymer exhibits good fluorescence properties in the solid state at room temperature and its thermogravimetric properties are also described.
引用
收藏
页码：490 / 493
页数：4
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