Quantitative control of RTM6 epoxy resin polymerisation by optical index determination

被引:28
作者
Aduriz, X. A.
Lupi, C.
Boyard, N.
Bailleul, J. -L.
Leduc, D.
Sobotka, V.
Lefevre, N.
Chapeleau, X.
Boisrobert, C.
Delaunay, D.
机构
[1] Univ Nantes, Fac Sci & Tech, IREENA EA 1770, F-44322 Nantes, France
[2] Univ Nantes, CNRS, LTN UMR 6607, F-440306 Nantes, France
关键词
smart materials; curing; optical fibre sensor;
D O I
10.1016/j.compscitech.2007.04.008
中图分类号
TB33 [复合材料];
学科分类号
摘要
RTM6 epoxy resin curing is usually characterized by the polymerisation degree. We report in this paper on a refractive index measurement technique applied on an experimental mould to control, quantitatively and in situ, the industrial RTM process. For the first time, we determined simultaneously the thermo-optical coefficient, the refractive index evolution, the specific volume and the polymerisation degree of the resin. The calculation of a "polymerisation degree optical coefficient" led to a quantification of the RTM6 epoxy resin polymerisation process. This calibration coefficient is very useful to perform a real time industrial process control. Furthermore, the optoelectronic system is connected to a data processing unit and is easy to use in an industrial environment. (C) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3196 / 3201
页数:6
相关论文
共 16 条
[1]   FIBER OPTIC POLYMER CURE SENSOR [J].
AFROMOWITZ, MA .
JOURNAL OF LIGHTWAVE TECHNOLOGY, 1988, 6 (10) :1591-1594
[2]   Real time monitoring of cure and gelification of a thermoset matrix [J].
Antonucci, V. ;
Giordano, M. ;
Cusano, A. ;
Nasser, J. ;
Nicolais, L. .
COMPOSITES SCIENCE AND TECHNOLOGY, 2006, 66 (16) :3273-3280
[3]  
Beck J.V., 1985, INVERSE HEAT CONDUCT
[4]  
Born M, 2005, Principles of optics
[5]   Analysis and modeling of PVTX diagram of an unsaturated polyester resin, thermoplastic additive, and mineral fillers blend [J].
Boyard, N ;
Vayer, M ;
Sinturel, C ;
Erre, R ;
Delaunay, D .
JOURNAL OF APPLIED POLYMER SCIENCE, 2003, 88 (05) :1258-1267
[6]   In situ study of the epoxy cure process using a fibre-optic sensor [J].
Chailleux, E ;
Salvia, M ;
Jaffrezic-Renault, N ;
Matejec, V ;
Kasik, I .
SMART MATERIALS & STRUCTURES, 2001, 10 (02) :194-202
[7]   In situ cure monitoring of epoxy resins using optical fibre sensors [J].
Crosby, PA ;
Powell, GR ;
Fernando, GF ;
France, CM ;
Spooncer, RC ;
Waters, DN .
SMART MATERIALS & STRUCTURES, 1996, 5 (04) :415-428
[8]   An optoelectronic sensor for cure monitoring in thermoset-based composites [J].
Cusano, A ;
Breglio, G ;
Giordano, M ;
Calabrò, A ;
Cutolo, A ;
Nicolais, L .
SENSORS AND ACTUATORS A-PHYSICAL, 2000, 84 (03) :270-275
[9]   Optoelectronic characterization of the curing process of thermoset-based composites [J].
Cusano, A ;
Breglio, G ;
Giordano, M ;
Calabrò, A ;
Cutolo, A ;
Nicolais, L .
JOURNAL OF OPTICS A-PURE AND APPLIED OPTICS, 2001, 3 (02) :126-130
[10]   Kinetic modeling of an unsaturated polyester resin using two complementary techniques: Near infrared spectroscopy and heat flux sensors [J].
Dupuy, J ;
Adami, J ;
Maazouz, A ;
Sobotka, V ;
Delaunay, D .
POLYMER ENGINEERING AND SCIENCE, 2005, 45 (06) :846-856