The reaction of methanol to hydrocarbons:: Effect of adding Cu2+ to ZSM-5 using [Cu(en)2]2+ by ion exchange

被引：0

作者：

Rao, SNR ^{[1
]}

White, MG ^{[1
]}

机构：

[1] Georgia Inst Technol, Sch Chem Engn, Focused Res Program Surface Sci & Catalysis, Atlanta, GA 30332 USA

来源：

CATALYSIS OF ORGANIC REACTIONS | 1998年 / 75卷

关键词：

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two series of catalysts were prepared for which Cu2+ ions were introduced into the zeolite ZSM-5. For one series, an aqueous solution of Cu(OAc)(2) was the sources of the Cu2+ ions; and for the other series, Cu(en)(2)(ClO4)(2) dissolved in acetonitrile was the source of the Cu2+ ions. These catalysts were tested for reactivity and selectivity in the methanol to hydrocarbon reaction. The selectivity of this reaciton to C-8-C-10 hydrocarbons was favored by the catalyst prepared using Cu(en)(2)(ClO4)(2) as the source of Cu2+ ions.

引用

页码：63 / 74

页数：12