Synthesis and Characterization of Donor-Functionalized N,S-Compounds Containing the ortho-Aminothiophenol Motif

被引：13

作者：

Cross, Edward D. ^{[1
]}

Shehzad, Usman A. ^{[1
]}

Lloy, Samantha M. ^{[1
]}

Brown, Adam R. C. ^{[1
]}

Mercer, Todd D. ^{[1
]}

Foster, Daniel R. ^{[1
]}

McLellan, Beth L. ^{[1
]}

Murray, Alexander R. ^{[1
]}

English, Margaret A. ^{[1
]}

Bierenstiel, Matthias ^{[1
]}

机构：

[1] Cape Breton Univ, Dept Chem, Sydney, NS B1P 6L2, Canada

来源：

SYNTHESIS-STUTTGART | 2011年 / 02期

基金：

加拿大自然科学与工程研究理事会; 加拿大创新基金会;

关键词：

Schiff bases; sulfur; nitrogen; ligands; alkylation; REGIOSELECTIVE MERCURATION; ELECTRONIC-STRUCTURES; IONOPHORE CHARACTER; EXCITED-STATE; COMPLEXES; LIGANDS; 2-AMINOTHIOPHENOL; REARRANGEMENTS; COORDINATION; NONINNOCENCE;

D O I：

10.1055/s-0030-1258352

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of twenty S-benzyl ortho-aminothiophenol and S,S'-xylylene-bridged bis(ortho-aminothiophenol) compounds and their imine derivatives have been synthesized in moderate to excellent yields and characterized. The syntheses were optimized, including large-scale syntheses, and an improved purification method involving the HCl salt was developed. This paper also serves as a comprehensive review of xylylene-bridged bis(ortho-aminothiophenol) compounds.

引用

页码：303 / 315

页数：13

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