New Heterocyclic Derivative to Stop Carbon Steel Corrosion

被引:3
作者
Deyab, M. A. [1 ]
Fouda, A. S. [2 ]
Abdel-Fattah, S. [1 ]
机构
[1] EPRI, POB 11727, Cairo, Egypt
[2] Mansoura Univ, Fac Sci, Dept Chem, Mansoura, Egypt
来源
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS | 2020年 / 234卷 / 01期
关键词
acid solution; corrosion inhibitor; electrochemical; FT-IR; heterocycle; MILD-STEEL; ELECTROCHEMICAL INVESTIGATIONS; COOLING WATER; INHIBITION; ACID; ADSORPTION; BEHAVIOR; SURFACTANT; ALUMINUM; METHIONINE;
D O I
10.1515/zpch-2019-1399
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The new compound 4-(2-(1,5- dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)hydrazono)-3-methyl-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothioamide (PY) was synthesized. Its anti-corrosion properties for C-steel in acid solution (1.0 M HCl) were evaluated utilize electrochemical tools. The synthesized compound was described using FT-IR and H-1-NMR analyses. The purity of PY was affirmed by thin-layer chromatography (TLC). The outcome data proved that PY possess adequate anti-corrosion features for C-steel in corrosive solution. The polarization parameters mentioned that the PY is a mixed inhibitor. Inhibition performance obtained by polarization measurements (i.e. 91.5%) are consistent with the one obtained by EIS (i.e. 88.6%). Quantum chemical parameters for PY were studied to supply assist knowledge into the anti-corrosion properties of the new compound.
引用
收藏
页码:63 / 73
页数:11
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