High flux polyaniline-coated ceramic membrane for effective separation of emulsified oil-in-water

被引:19
作者
Salhi, Billel [1 ]
Baig, Nadeem [1 ]
Abdulazeez, Ismail [1 ]
Al-Ahmed, Amir [2 ]
Aljundi, Isam H. [1 ,3 ]
机构
[1] KFUPM, Interdisciplinary Res Ctr Membranes & Water Secur, Dhahran, Saudi Arabia
[2] KFUPM, Interdisciplinary Res Ctr Renewable Energy & Powe, Dhahran, Saudi Arabia
[3] King Fahd Univ Petr & Minerals, Chem Engn Dept, Dhahran 31261, Saudi Arabia
关键词
Demulsification; Ceramic membrane; Hybrid membranes; Polyaniline; Oil/water separation; MICROFILTRATION; NANOCOMPOSITES; SPECTRA;
D O I
10.1016/j.ceramint.2022.05.189
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Oil separation from oily wastewater is critical for environmental sustainability. In the present study, we report for the first time the facile fabrication of high flux polyaniline-modified ceramic membrane to effectively separate emulsified oil. Aniline was rapidly polymerized in a single step on alumina ceramic support using different monomer concentrations. It was revealed that the alumina membrane modified with 1.0 M aniline monomer is suitable for separating oil/water emulsions with an exceptionally high permeance of 3451 L m(-2).h(-1) (L.M.H.) and high separating efficiency. The polyaniline-coated alumina membranes appeared superhydrophilic/ superoleophobic w ith negligible fouling behavior. The modified membranes demonstrate a steady oil rejection flux after several cycles with excellent oil-rejection of 97%. The high flux, low operating pressure, and anti-fouling behavior revealed that these modified membranes are excellent candidates for emulsified-oil separation.
引用
收藏
页码:25246 / 25253
页数:8
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