Partial Molar Isentropic Compressions and Partial Molar Volumes of Selected Branched Aliphatic Alcohols at Infinite Dilution in Water at Temperatures from T = (278 to 318) K and Atmospheric Pressure

被引:21
作者
Simurka, Lukas [1 ]
Cibulka, Ivan [1 ]
Hnedkovsky, Lubomir [1 ]
机构
[1] Inst Chem Technol, Dept Phys Chem, CR-16628 Prague, Czech Republic
关键词
VIBRATING-TUBE DENSIMETER; AQUEOUS-SOLUTIONS; ORGANIC SOLUTES; 30; MPA; COMPRESSIBILITIES; PROPANE; ETHERS;
D O I
10.1021/je300175w
中图分类号
O414.1 [热力学];
学科分类号
摘要
Speed of sound data for dilute aqueous solutions of one monohydric alcohol (2,2-dimethylpropane-1-ol), five polyhydric alcohols (2-methylpropane-1,3-diol, 2,2-dimethylpropane-1,3-diol, 2,2-bis(hydroxymethyl)propane-1-ol, 2,2-bis(hydroxymethyl)propane-1,3-diol, 2,2-bis(hydroxymethyl)butane-1-ol), and one ether alcohol (3,3,7,7-tetrakis(hydroxymethyl)-5-oxanonane) were obtained using the Anton Paar DSA 5000 vibrating-tube densimeter and sound analyzer in the temperature range from (278.15 to 318.15) K and at atmospheric pressure. Standard molar isentropic compressions were evaluated from the measured data. Measured densities of dilute aqueous solutions of 2,2-dimethylpropane-1,3-diol and 2,2-bis(hydroxymethyl)propane-1,3-diol are also presented along with the standard molar volumes of these two solutes calculated from the measured standard quantities and molecular structures of the solutes are discussed.
引用
收藏
页码:1570 / 1580
页数:11
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