Embodied Energy in Pyrolysis and Solvolysis Approaches to Recycling for Carbon Fiber-Epoxy Reinforced Composite Waste Streams

被引:21
作者
Kooduvalli, Komal [1 ,2 ,3 ]
Unser, John [2 ]
Ozcan, Soydan [2 ,3 ]
Vaidya, Uday K. [1 ,2 ,3 ]
机构
[1] Univ Tennessee, Fibers & Composites Mfg Facil, 1321 White Ave, Knoxville, TN 37996 USA
[2] Inst Adv Composites Mfg Innovat IACMI, 2360 Cherahala Blvd, Knoxville, TN 37932 USA
[3] Oak Ridge Natl Lab, Mfg Sci Div, 1 Bethel Valley Rd, Oak Ridge, TN 37831 USA
关键词
recycling; composites; embodied energy; pyrolysis; solvolysis; life cycle assessment; POLYMERS; TECHNOLOGIES; CFRPS;
D O I
10.3390/recycling7010006
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Carbon fiber composites are increasingly used in aerospace, motorcycles, sporting, and high-performance vehicles, and their end of life recycling is of growing interest. This study deals with the life cycle assessment (LCA) of carbon fiber reinforced plastics (CFRP) waste streams. The embodied energy (EE) of recycling CFRP via two viable methods-i.e., pyrolysis and solvolysis-is studied. Both pyrolysis and solvolysis were studied for EE with different variants. Alongside fiber recovery from CFRP, the pyrolysis process calculations consider energy recovery from syngas and oil produced within the system. For pyrolysis, electric furnace and natural gas were primarily considered. For solvolysis, different solvent scenarios were considered, including (a) deionized water, (b) water and potassium hydroxide, (c) acetone and water, and (d) water with acetic acid and potassium hydroxide. Energy reduction from one generation to the next has also been highlighted. The EE for recycling CFRP is quantified and discussed for these scenarios in this paper.
引用
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页数:13
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