Toward carboxylate group functionalized A4, A2B2, A3B oxaporphyrins and zinc complex of oxaporphyrins

被引：14

作者：

Ambre, Ram ^{[1
,2
]}

Yu, Chien-Yi ^{[1
,2
]}

Mane, Sandeep B. ^{[1
,2
]}

Yao, Ching-Fa ^{[2
]}

Hung, Chen-Hsiung ^{[1
]}

机构：

[1] Acad Sinica, Inst Chem, Taipei 115, Taiwan

[2] Natl Taiwan Normal Univ, Dept Chem, Taipei 11677, Taiwan

来源：

TETRAHEDRON | 2011年 / 67卷 / 25期

关键词：

Porphyrin Synthesis; Core-Modified Porphyrin; Oxaporphyrin; Zinc Porphyrin; X-ray structure; 21-OXAPORPHYRIN BUILDING-BLOCKS; CORE-MODIFIED PORPHYRINS; SENSITIZED SOLAR-CELLS; PHOTODYNAMIC THERAPY; COPPER(II) COMPLEXES; ELECTRON-TRANSFER; APPENDED SYSTEMS; IRON; 21-THIAPORPHYRIN; NICKEL(II);

D O I：

10.1016/j.tet.2011.04.034

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Series of new oxaporphyrins were isolated from the reaction of furan-1,4-diol, pyrrole, and an aldehyde under Lindsey's conditions, which gives easy access to ester group functionalized oxaporphyrins. The ester substituents can be readily hydrolyzed to terminal carboxylic acid in the presence of KOH. The Zn(II) oxaporphyrins have been synthesized from the reaction of free base with ZnCl2 and fully characterized by variable temperature NMR, 2D NMR, and single crystal X-ray diffraction studies. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：4680 / 4688

页数：9

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