A meso-Spiro[Cyclopentadiene-Isoporphyrin] from a Phenylethynyl Porphyrin Platinum(II) Pincer Complex

被引：16

作者：

Anabuki, Shoma ^{[3
]}

Shinokubo, Hiroshi ^{[1
]}

Aratani, Naoki ^{[2
,3
]}

Osuka, Atsuhiro ^{[3
]}

机构：

[1] Nagoya Univ, Dept Appl Chem, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan

[2] Japan Sci & Technol Agcy, PRESTO, Tokyo, Japan

[3] Kyoto Univ, Dept Chem, Grad Sch Sci, Sakyo Ku, Kyoto 6068502, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 13期

关键词：

isoporphyrins; pincer ligands; platinum; porphyrinoids; reductive elimination; PERIPHERALLY-METALATED PORPHYRINS; HORSERADISH-PEROXIDASE; CRYSTAL-STRUCTURES; ZINC ISOPORPHYRIN; AQUEOUS-SOLUTION; OXIDATION; PHOTOOXIDATION; MECHANISM; PLATINIOPORPHYRINS; TAUTOMERIZATION;

D O I：

10.1002/anie.201109091

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A good catch: The oxidation of a phenylethynyl Pt II pincer complex with iodine led to formal reductive elimination but without the liberation of Pt II, which was caught by the 2-pyridyl substituents on the Ni II porphyrin. The unique reactivity of the Pt II pincer complex led to the formation of a meso-spiro[cyclopentadiene- isoporphyrin]. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：3174 / 3177

页数：4

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