Remote activation of nickel complexes by coordination of B(C6F5)3 to an exocyclic carbonitrile functionality

被引：36

作者：

Boardman, Brycelyn M. ^{[1
]}

Valderrama, Juan M. ^{[1
]}

Munoz, Flor ^{[1
]}

Wu, Guang ^{[1
]}

Bazan, Guillermo C. ^{[1
]}

Rojas, Rene ^{[1
]}

机构：

[1] Pontificia Univ Catolica Chile, Fac Quim, Dept Quim Inorgan, Santiago 22, Chile

来源：

ORGANOMETALLICS | 2008年 / 27卷 / 08期

关键词：

D O I：

10.1021/om700933y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of two new organometallic species, compounds I and 2, allows for the investigation of remote activation through an exocyclic CN functionality. The in situ generation of 2 from 1 plus excess B(C6F5)(3) yields polyethylene possessing a bimodal distribution.

引用

页码：1671 / 1674

页数：4

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