Synthesis of an Amphiphilic Miktoarm Star Terpolymer for Self-Assembly into Patchy Polymersomes

被引：31
|
作者：
Gaitzsch, Jens [1 ,2 ]
Chudasama, Vijay [1 ]
Morecroft, Eloise [1 ,3 ]
Messager, Lea [1 ]
Battaglia, Giuseppe [1 ]
机构：
[1] UCL, Dept Chem, 20 Gordon St, London WC1H 0AJ, England
[2] Univ Basel, Dept Chem, Klingelbergstr 80, CH-4056 Basel, Switzerland
[3] Univ London Imperial Coll Sci Technol & Med, Inst Chem Biol, Exhibit Rd, London SW7 2AZ, England
来源：
ACS MACRO LETTERS | 2016年 / 5卷 / 03期
关键词：
BLOCK-COPOLYMER VESICLES; RESPONSIVE POLYMERSOMES; DELIVERY; PH; CHEMISTRY; ENCAPSULATION; TEMPERATURE; CONJUGATION; NANOSCALE; MICELLES;
D O I：
10.1021/acsmacrolett.5b00913
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Herein we report the synthesis of an amphiphilic miktoarm star terpolymer and combine it with an equivalent diblock copolymer to form polymersomes with controlled surface topology. The three branches are ligated onto a central maleimide moiety in a reaction sequence that exploits various "click" chemistries. The final star was self-assembled with a linear block copolymer to generate a "patchy" surface on vesicles.
引用
收藏
页码：351 / 354
页数：4
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