Improving the performance of lithium-ion batteries by using spinel nanoparticles

被引:12
作者
Arrebola, J. C. [1 ]
Caballero, A. [1 ]
Hernan, L. [1 ]
Morales, J. [1 ]
机构
[1] Univ Cordoba, Dept Quim Inorgan & Ingn Quim, E-14071 Cordoba, Spain
关键词
D O I
10.1155/2008/659397
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this work, we examined the use of nanospinels to construct batttery electrodes. We chose two spinels suitable as cathode materials (LiMn2O4 and LiNi0.5Mn1.5O4, which are representative of 4 and 5 V versus Li metal, resp.) and one providing good results as anode (Li4Ti5O12). In order to ensure good cell performance, nanometric particles must meet another requirement; thus they should contain few surface or bulk defects (i.e., they should be highly crystalline). Because the synthesis of such spinels usually requires a thermal treatment, ensuring that they will meet both requirements entails accuratly controlling in the synthesis conditions. Thermal decomposition of nanooxalate in the spinel-conaining elements obtained by mechanochenical activation in the presence of polymers provides a simple, effective route for this purpose. We prepared two types of hybrid lithium-ion batteries using LiMn2O4 and LiNi0.5Mn1.5O4 as cathode materials, and Li4Ti5O12 as anode material. The electrochemical properties of these cells were compared with those of a similar configuration made from micrometric particles. The nano-nano configuration exhibited higher reversibility and better performance than the micro-micro configuartion in both types of cells, possibly as a result of lithium ions in the former being able to migrate more easily into the electrode material. Copyright (c) 2008 J.C. Arrebola et al.
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页数:10
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共 35 条
[1]   Nanostructured materials for advanced energy conversion and storage devices [J].
Aricò, AS ;
Bruce, P ;
Scrosati, B ;
Tarascon, JM ;
Van Schalkwijk, W .
NATURE MATERIALS, 2005, 4 (05) :366-377
[2]   Topotactic two-phase reactions of Li[Ni1/2Mn3/2]O4 (P4332) in nonaqueous lithium cells [J].
Ariyoshi, K ;
Iwakoshi, Y ;
Nakayama, N ;
Ohzuku, T .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (02) :A296-A303
[3]   TiO2(B) nanowires as an improved anode material for lithium-ion batteries containing LiFePO4 or LiNi0.5Mn1.5O4 cathodes and a polymer electrolyte [J].
Armstrong, Graham ;
Armstrong, A. Robert ;
Bruce, Peter G. ;
Reale, Priscilla ;
Scrosati, Bruno .
ADVANCED MATERIALS, 2006, 18 (19) :2597-+
[4]   Effects of coating with gold on the performance of nanosized LiNi0.5Mn1.5O4 for lithium batteries [J].
Arrebola, J. ;
Caballero, A. ;
Hernan, L. ;
Morales, J. ;
Castellon, E. Rodriguez ;
Barrado, J. R. Ramos .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (03) :A178-A184
[5]   High performance hybrid lithium-ion batteries based on combinations of nanometric materials [J].
Arrebola, J. C. ;
Caballero, A. ;
Hernan, L. .
NANOTECHNOLOGY, 2007, 18 (29)
[6]   Expanding the rate capabilities of the LiNi0.5Mn1.5O4 spinel by exploiting the synergistic effect between nano and microparticles [J].
Arrebola, JC ;
Caballero, A ;
Hernán, L ;
Morales, J .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2005, 8 (12) :A641-A645
[7]   Crystallinity control of a nanostructured LiNi0.5Mn1.5O4 spinet via polymer-assisted synthesis:: A method for improving its rate capability and performance in 5 V lithium batteries [J].
Arrebola, Jose C. ;
Caballero, Alvaro ;
Cruz, Manuel ;
Hernan, Lourdes ;
Morales, Julian ;
Castellon, Enrique Rodriguez .
ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (14) :1904-1912
[8]   Cathodes for lithium ion batteries: The benefits of using nanostructured materials [J].
Bazito, Fernanda F. C. ;
Torresi, Roberto M. .
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2006, 17 (04) :627-642
[9]   Nanocrystalline materials obtained by using a simple, rapid method for rechargeable lithium batteries [J].
Caballero, A ;
Cruz, M ;
Hernán, L ;
Melero, M ;
Morales, J ;
Castellón, ER .
JOURNAL OF POWER SOURCES, 2005, 150 :192-201
[10]   LiMn2-xCuxO4 spinels (0.1≤x≤0.5):: A new class of 5 V cathode materials for Li batteries -: I.: Electrochemical, structural, and spectroscopic studies [J].
Ein-Eli, Y ;
Howard, WF ;
Lu, SH ;
Mukerjee, S ;
McBreen, J ;
Vaughey, JT ;
Thackeray, MM .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (04) :1238-1244