共 35 条
Improving the performance of lithium-ion batteries by using spinel nanoparticles
被引:12
作者:

Arrebola, J. C.
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机构:
Univ Cordoba, Dept Quim Inorgan & Ingn Quim, E-14071 Cordoba, Spain Univ Cordoba, Dept Quim Inorgan & Ingn Quim, E-14071 Cordoba, Spain

Caballero, A.
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Univ Cordoba, Dept Quim Inorgan & Ingn Quim, E-14071 Cordoba, Spain Univ Cordoba, Dept Quim Inorgan & Ingn Quim, E-14071 Cordoba, Spain

Hernan, L.
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Univ Cordoba, Dept Quim Inorgan & Ingn Quim, E-14071 Cordoba, Spain Univ Cordoba, Dept Quim Inorgan & Ingn Quim, E-14071 Cordoba, Spain

Morales, J.
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Univ Cordoba, Dept Quim Inorgan & Ingn Quim, E-14071 Cordoba, Spain Univ Cordoba, Dept Quim Inorgan & Ingn Quim, E-14071 Cordoba, Spain
机构:
[1] Univ Cordoba, Dept Quim Inorgan & Ingn Quim, E-14071 Cordoba, Spain
关键词:
D O I:
10.1155/2008/659397
中图分类号:
TB3 [工程材料学];
学科分类号:
0805 ;
080502 ;
摘要:
In this work, we examined the use of nanospinels to construct batttery electrodes. We chose two spinels suitable as cathode materials (LiMn2O4 and LiNi0.5Mn1.5O4, which are representative of 4 and 5 V versus Li metal, resp.) and one providing good results as anode (Li4Ti5O12). In order to ensure good cell performance, nanometric particles must meet another requirement; thus they should contain few surface or bulk defects (i.e., they should be highly crystalline). Because the synthesis of such spinels usually requires a thermal treatment, ensuring that they will meet both requirements entails accuratly controlling in the synthesis conditions. Thermal decomposition of nanooxalate in the spinel-conaining elements obtained by mechanochenical activation in the presence of polymers provides a simple, effective route for this purpose. We prepared two types of hybrid lithium-ion batteries using LiMn2O4 and LiNi0.5Mn1.5O4 as cathode materials, and Li4Ti5O12 as anode material. The electrochemical properties of these cells were compared with those of a similar configuration made from micrometric particles. The nano-nano configuration exhibited higher reversibility and better performance than the micro-micro configuartion in both types of cells, possibly as a result of lithium ions in the former being able to migrate more easily into the electrode material. Copyright (c) 2008 J.C. Arrebola et al.
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共 35 条
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