Activated clay of nest structure encapsulated sulfur cathodes for lithium-sulfur batteries

被引:8
作者
Cao, Zhaoxia [1 ,2 ,3 ]
Ma, Chao [1 ,2 ,3 ]
Jia, Yujie [1 ,2 ,3 ]
Sun, Zhixian [1 ,2 ,3 ]
Yue, Hongyun [1 ,2 ,3 ]
Yin, Yanhong [1 ,2 ,3 ]
Yang, Shuting [1 ,2 ,3 ]
机构
[1] Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China
[2] Engn Technol Res Ctr Mot Power & Key Mat Henan Pr, Xinxiang 453007, Henan, Peoples R China
[3] Henan Normal Univ, Collaborat Innovat Ctr Henan Prov Green Mot Power, Xinxiang 453007, Henan, Peoples R China
关键词
LI-S BATTERIES; COMPOSITE; GRAPHENE; SYSTEM; CELLS;
D O I
10.1039/c5ra02369f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Activated clay (AC) with a nest-like structure and a large surface area was employed to support sulfur as the cathode for lithium-sulfur batteries. The special structure may have a similar effect to small filter screens for entrapping sulfur and restricting the diffusion of polysulfides during cycling. A high capacity of 959.6 mA h g(-1) was achieved at a rate of 0.1 C in the first cycle for the AC/S composite with a sulfur content of 57 wt% and the reversible capacity remained high at up to 700.9 mA h g(-1) even after 50 cycles.
引用
收藏
页码:28349 / 28353
页数:5
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