Defunctionalization of fructose and sucrose: Iron-catalyzed production of 5-hydroxymethylfurfural from fructose and sucrose

被引：72

作者：

Tong, Xinli ^{[1
,2
]}

Li, Mengran ^{[1
,2
]}

Yan, Ning ^{[3
]}

Ma, Yang ^{[1
,2
]}

Dyson, Paul J. ^{[3
]}

Li, Yongdan ^{[1
,2
]}

机构：

[1] Tianjin Univ, Sch Chem Engn, Tianjin Key Lab Catalysis Sci & Technol, Tianjin 300072, Peoples R China

[2] Tianjin Univ, Sch Chem Engn, State Key Lab Chem Engn, Tianjin 300072, Peoples R China

[3] Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland

来源：

CATALYSIS TODAY | 2011年 / 175卷 / 01期

基金：

中国博士后科学基金;

关键词：

Fructose; Sucrose; 5-Hydroxymethylfurfural; Iron catalysis; Biomass transformation; CONVERSION; DEHYDRATION; BIOMASS; ACID; EFFICIENT; SUGARS; 5-HYDROXYMETHYL-2-FURALDEHYDE; OXIDATION; CHLORIDES; LIQUIDS;

D O I：

10.1016/j.cattod.2011.03.003

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A highly efficient iron-catalyzed production of 5-hydroxymethylfurfural (HMF) from sugar is reported. The dehydration of fructose and sucrose has been studied in the presence of different iron salts and co-catalysts. As a result, it was found that fructose and sucrose could be efficiently and selectively converted to HMF using a combination of environmentally friendly FeCl3 and tetraethyl ammonium bromide (Et4NBr) as the catalytic system. For instance, 86% HMF yield at full conversion of fructose was obtained for 2 h at 90 degrees C in air. The effects of catalyst concentration, reaction time and reaction temperature were investigated in detail. The electronic absorption spectra of different catalysts were recorded, and the FeCl3Br- ion was considered as the active catalyst species. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：524 / 527

页数：4

共 42 条

[1] Acid-catalyzed production of 5-hydroxymethyl furfural from D-fructose in subcritical water [J].

Asghari, FS ;

Yoshida, H .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (07) :2163-2173

[2] Preparation of 5-hydroymethylfurfural by dehydration of fructose in the presence of acidic ionic liquid [J].

Bao, Quanxi ;

Qiao, Kun ;

Tomida, Daisuke ;

Yokoyama, Chiaki .

CATALYSIS COMMUNICATIONS, 2008, 9 (06) :1383-1388

[3] Dehydration of fructose to 5-hydroxymethylfurfural in sub- and supercritical acetone [J].

Bicker, M ;

Hirth, J ;

Vogel, H .

GREEN CHEMISTRY, 2003, 5 (02) :280-284

[4] Catalytical conversion of carbohydrates in subcritical water: A new chemical process for lactic acid production [J].

Bicker, M ;

Endres, S ;

Ott, L ;

Vogel, H .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 239 (1-2) :151-157

[5] Iron-catalyzed reactions in organic synthesis [J].

Bolm, C ;

Legros, J ;

Le Paih, J ;

Zani, L .

CHEMICAL REVIEWS, 2004, 104 (12) :6217-6254

[6] Selective Conversion of Fructose to 5-Hydroxymethylfurfural Catalyzed by Tungsten Salts at Low Temperatures [J].

Chan, Jin Young Gerentt ;

Zhang, Yugen .

CHEMSUSCHEM, 2009, 2 (08) :731-734

[7] Liquid-phase catalytic processing of biomass-derived oxygenated hydrocarbons to fuels and chemicals [J].

Chheda, Juben N. ;

Huber, George W. ;

Dumesic, James A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (38) :7164-7183

[8] Chemical routes for the transformation of biomass into chemicals [J].

Corma, Avelino ;

Iborra, Sara ;

Velty, Alexandra .

CHEMICAL REVIEWS, 2007, 107 (06) :2411-2502

[9]

Figgis B.N., 2000, LIGAND FIELD THEORY, P138

[10] Advances in iron catalyzed cross coupling reactions [J].

Fürstner, A ;

Martin, R .

CHEMISTRY LETTERS, 2005, 34 (05) :624-629

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