New framework iodoargentates:: M(en)3Ag2I4 (M = Zn, Ni) with tridymite topology

被引：70

作者：

Jiang, Yan-Si ^{[1
]}

Yao, Hua-Gang ^{[1
]}

Ji, Shou-Hua

Ji, Min ^{[1
,2
]}

An, Yong-Lin ^{[1
]}

机构：

[1] Dalian Univ Technol, Dept Chem, Dalian 116024, Peoples R China

[2] Dalian Univ Technol, Dept Mat, Dalian 116024, Peoples R China

来源：

INORGANIC CHEMISTRY | 2008年 / 47卷 / 10期

关键词：

D O I：

10.1021/ic7025158

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel framework compounds, Zn(en)(3)Ag2I4 (1) and Ni(en)(3)Ag2I4 (2), have been synthesized by a self-assembly reaction. Both of them contain an unexpected framework, Ag2I42- with tridymite topolopy, and the discrete M(en)(3)(2+) cations are located in the channels. Their thermal properties and circular dichroism spectra were investigated.

引用

页码：3922 / 3924

页数：3

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