Comparative parametric study on development of porous structure of aluminium oxide in presence of anionic and cationic surfactants

被引：18

作者：

Patel, Chirag Kumar ^{[1
]}

Sarma, Paran Jyoti ^{[1
]}

De, Mahuya ^{[1
]}

机构：

[1] Indian Inst Technol Guwahati, Dept Chem Engn, Gauhati 781039, Assam, India

来源：

CERAMICS INTERNATIONAL | 2015年 / 41卷 / 03期

关键词：

Aluminium oxide; Porous structure; Precipitation; CTAB; SDS; ORGANIZED MESOPOROUS ALUMINA; DODECYL-SULFATE; PRECIPITATION; HYDROLYSIS; MICELLES; TEMPERATURE; TRANSITION; POROSITY; SHAPE; SIZE;

D O I：

10.1016/j.ceramint.2014.10.186

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Aluminium oxide was prepared from aluminium nitrate by precipitation in presence of cationic cetyl trimethyl ammonium bromide (CTAB) and anionic sodium dodecyl sulfate (SDS) surfactants. Effects of surfactant type and concentration, pH, aging temperature and aging time on development of porous structure of aluminium oxide were investigated and compared. Surface area of samples prepared with CTAB was higher compared to that prepared with SDS at all preparation conditions. Mainly mesopores were obtained with SDS, whereas in presence of CTAB micropores were also obtained, particularly at lower surfactant concentration. The bayerite and boehmite were predominant structures in presence of CTAB and SDS, respectively. Formation of mesopores was favored at higher pH in presence of SDS and at lower pH in presence of CTAB. Surface area and pore volume of aluminium oxide increased with aging time in presence of SDS, but the effect was not significant for CTAB. (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.

引用

页码：3578 / 3588

页数：11

共 30 条

[1] Influence of the thermal treatment upon the textural properties of sol-gel mesoporous γ-alumina synthesized with cationic surfactants [J].

Aguado, J. ;

Escola, J. M. ;

Castro, M. C. .

MICROPOROUS AND MESOPOROUS MATERIALS, 2010, 128 (1-3) :48-55

[2] Sphere-to-rod transition in the shape of anionic surfactant micelles determined by surface tension measurements [J].

Alargova, RG ;

Danov, KD ;

Petkov, JT ;

Kralchevsky, PA ;

Broze, G ;

Mehreteab, A .

LANGMUIR, 1997, 13 (21) :5544-5551

[3] Synthesis of high-surface-area γ-Al2O3 from aluminum scrap and its use for the adsorption of metals: Pb(II), Cd(II) and Zn(II) [J].

Asencios, Yvan J. O. ;

Sun-Kou, Maria R. .

APPLIED SURFACE SCIENCE, 2012, 258 (24) :10002-10011

[4] Organized mesoporous alumina: synthesis, structure and potential in catalysis [J].

Cejka, J .

APPLIED CATALYSIS A-GENERAL, 2003, 254 (02) :327-338

[5] Structural transition in micelles: novel insight into microenvironmental changes in polarity and dynamics [J].

Chaudhuri, Arunima ;

Haldar, Sourav ;

Chattopadhyay, Amitabha .

CHEMISTRY AND PHYSICS OF LIPIDS, 2012, 165 (04) :497-504

[6] Sol-gel synthesis of mesostructured aluminas from chemically modified aluminum sec-butoxide using non-ionic surfactant templating [J].

González-Peña, V ;

Márquez-Alvarez, C ;

Díaz, I ;

Grande, M ;

Blasco, T ;

Pérez-Pariente, J .

MICROPOROUS AND MESOPOROUS MATERIALS, 2005, 80 (1-3) :173-182

[7] MICELLE SIZE AND SHAPE OF SODIUM DODECYL-SULFATE IN CONCENTRATED NACL SOLUTIONS [J].

HAYASHI, S ;

IKEDA, S .

JOURNAL OF PHYSICAL CHEMISTRY, 1980, 84 (07) :744-751

[8] Influence of precipitation conditions (pH and temperature) on the morphology and porosity of boehmite particles [J].

Hochepied, JF ;

Nortier, P .

POWDER TECHNOLOGY, 2002, 128 (2-3) :268-275

[9] Formation of mesoporous alumina via hydrolysis of modified aluminum isopropoxide in presence of CTAB cationic surfactant [J].

Khalil, Kamal M. S. .

APPLIED SURFACE SCIENCE, 2008, 255 (05) :2874-2878

[10] Cerium modified MCM-41 nanocomposite materials via a nonhydrothermal direct method at room temperature [J].

Khalil, Kamal Mohamed Sayed .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2007, 315 (02) :562-568

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