Structural direction by the dominant metal

被引:34
作者
Beswick, MA [1 ]
Mosquera, MEG [1 ]
Wright, DS [1 ]
机构
[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 15期
关键词
D O I
10.1039/a800687c
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Assessment of the structures of a number of heterometallic alkali metal/p block metal complexes suggests that the p block metals have a dominant role in dictating the structures of these species, since generally greater covalency of the metal-ligand interactions leads to more geometrically rigid metal co-ordination.
引用
收藏
页码:2437 / 2443
页数:7
相关论文
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