Bifuran-bridged bisboranes: highly luminescent B-doped oligohetarenes

被引：7
作者：
Riensch, Nicolas Alexander
Fest, Maximilian
Fritze, Lars
Helbig, Andreas
Krummenacher, Ivo
Braunschweig, Holger
Helten, Holger [1 ]
机构：
[1] Julius Maximilians Univ Wurzburg, Inst Inorgan Chem, D-97074 Wurzburg, Germany
来源：
NEW JOURNAL OF CHEMISTRY | 2021年 / 45卷 / 33期
关键词：
BLOCK CO-MICELLES; CONJUGATED POLYMERS; ALPHA-OLIGOFURANS; MOLECULAR DESIGN; BORON; TRIARYLBORANE; THIOPHENE; SYSTEM; POLY(IMINOBORANE)S; PERSPECTIVES;
D O I：
10.1039/d0nj04297h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A series of bifuran-bridged bis(triarylboranes) have been synthesized via classical metathesis or catalytic silicon/boron exchange reactions, respectively. The products obtained are strongly luminescent, with quantum yields up to 85%, and reversibly twofold reduced via successive one-electron processes.
引用
收藏
页码：14920 / 14924
页数：5
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共 70 条
[1]   Synthesis and Properties of Benzo[d]dithieno[b,f]borepins [J].
Adachi, Yohei ;
Ohshita, Joji .
ORGANOMETALLICS, 2018, 37 (06) :869-881
[2]   Hybrid conjugated polymers with alternating dithienosilole or dithienogermole and tricoordinate boron units [J].
Adachi, Yohei ;
Ooyama, Yousuke ;
Ren, Yi ;
Yin, Xiaodong ;
Jakle, Frieder ;
Ohshita, Joji .
POLYMER CHEMISTRY, 2018, 9 (03) :291-299
[3]   Cyclolinear Oligo- and Poly(iminoborane)s: The Missing Link in Inorganic Main-Group Macromolecular Chemistry [J].
Ayhan, Ozan ;
Riensch, Nicolas A. ;
Glasmacher, Clemens ;
Helten, Holger .
CHEMISTRY-A EUROPEAN JOURNAL, 2018, 24 (22) :5883-5894
[4]   Poly(iminoborane)s: An Elusive Class of Main-Group Polymers? [J].
Ayhan, Ozan ;
Eckert, Thomas ;
Plamper, Felix A. ;
Helten, Holger .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (42) :13321-13325
[5]   Synthesis of the First Heteroaryl-Substituted Boryl Complexes: Strong Stabilizing Effects of Boron-Aryl π-Conjugation [J].
Braunschweig, Holger ;
Dewhurst, Rian D. ;
Kramer, Thomas .
INORGANIC CHEMISTRY, 2015, 54 (07) :3619-3623
[6]   Direct Hydroboration of B=B Bonds: A Mild Strategy for the Proliferation of B-B Bonds [J].
Braunschweig, Holger ;
Dewhurst, Rian D. ;
Hoerl, Christian ;
Phukan, Ashwini K. ;
Pinzner, Florian ;
Ullrich, Stefan .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (12) :3241-3244
[7]   1-Heteroaromatic-Substituted Tetraphenylboroles: π-π Interactions Between Aromatic and Antiaromatic Rings Through a B-C Bond [J].
Braunschweig, Holger ;
Damme, Alexander ;
Jimenez-Halla, J. Oscar C. ;
Hoerl, Christian ;
Krummenacher, Ivo ;
Kupfer, Thomas ;
Mailaender, Lisa ;
Radacki, Krzysztof .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (49) :20169-20177
[8]   BN- and BO-Doped Inorganic-Organic Hybrid Polymers with Sulfoximine Core Units [J].
Brosge, Felix ;
Lorenz, Thomas ;
Helten, Holger ;
Bolm, Carsten .
CHEMISTRY-A EUROPEAN JOURNAL, 2019, 25 (55) :12708-12711
[9]   α-Oligofurans: Molecules without a Twist [J].
Bunz, Uwe H. F. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (30) :5037-5040
[10]   Recent Advances in Conjugated Furans [J].
Cao, Hongda ;
Rupar, Paul A. .
CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (59) :14670-14675
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