A route to new methylpalladium(II) carbene complexes

被引：37

作者：

Green, MJ

Cavell, KJ

Skelton, BW

White, AH

机构：

[1] Univ Tasmania, Dept Chem, Hobart, Tas 7001, Australia

[2] Univ Western Australia, Dept Chem, Nedlands, WA 6907, Australia

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 554卷 / 02期

基金：

澳大利亚研究理事会;

关键词：

carbene complex; palladium; 1,3-dimethylimidazolin-2-ylidene;

D O I：

10.1016/S0022-328X(97)00671-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The nucleophilic carbene, 1,3-dimethylimidazolin-2-ylidene, reacts with PdClMe(cod) to produce the first methylpalladium(II) carbene complex, [PdMe(1,3-dimethylimidazolin-2-ylidene)(mu-Cl)](2) 1, from which the preparation of other methylpalladium carbene complexes may proceed, and the crystal structure of one such complex, [PdMe(1,3-dimethylimidazolin-2-ylidene)(NC5H4CO2-2)], is reported. (C) 1998 Elsevier Science S.A. All rights reserved.

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页码：175 / 179

页数：5

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