Direct synthesis of supported noble metal catalysts via the activated carbon route

被引:2
作者
Schwickardi, M [1 ]
Spliethoff, B [1 ]
Schmidt, W [1 ]
Schüth, F [1 ]
机构
[1] MPI Kohlenforsch, D-45470 Mulheim, Germany
来源
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS | 2005年 / 219卷 / 07期
关键词
supported catalyst; activated carbon; high surface area; nano particle; noble metal; small particle;
D O I
10.1524/zpch.219.7.939.67085
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Simultaneous impregnation of activated carbon with a base metal oxide precursor and a noble metal precursor with subsequent combustion of the activated carbon leads in one step to supported metal particles on very high surface area support oxides having specific surface areas of several hundred square metres per gram. For some of the noble metals (Rh, Fit) it is possible to synthesize supported particles in the size range of one to a few nanometers via this route.
引用
收藏
页码:939 / 948
页数:10
相关论文
共 13 条
[1]   FORMATION AND THERMAL-STABILITY OF RHODIUM OXIDES [J].
BAYER, G ;
WIEDEMANN, HG .
THERMOCHIMICA ACTA, 1976, 15 (02) :213-226
[2]   Application of a new color detection based method for the fast parallel screening of DeNOx catalysts [J].
Busch, OM ;
Hoffmann, C ;
Johann, TRF ;
Schmidt, HW ;
Strehlau, W ;
Schüth, F .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (45) :13527-13532
[3]  
ERTL G, 1997, HDB HETEROGENEOUS CA, P191
[4]   Rhodium-oxide species formed on progressive oxidation of rhodium clusters dispersed on alumina [J].
Hwang, CP ;
Yeh, CT ;
Zhu, QM .
CATALYSIS TODAY, 1999, 51 (01) :93-101
[5]   THE EFFECT OF ALUMINA PHASE-STRUCTURE ON THE DISPERSION OF RHODIUM/ALUMINA CATALYSTS [J].
MCCABE, RW ;
USMEN, RK ;
OBER, K ;
GANDHI, HS .
JOURNAL OF CATALYSIS, 1995, 151 (02) :385-393
[6]   Structure-activity correlations on Rh/Al2O3 and Rh/TiO2 thin film model catalysts after oxidation and reduction [J].
Rupprechter, G ;
Seeber, G ;
Goller, H ;
Hayek, K .
JOURNAL OF CATALYSIS, 1999, 186 (01) :201-213
[7]  
Schwickardi M, 2002, STUD SURF SCI CATAL, V143, P93
[8]   High-surface-area oxides obtained by an activated carbon route [J].
Schwickardi, M ;
Johann, T ;
Schmidt, W ;
Schüth, F .
CHEMISTRY OF MATERIALS, 2002, 14 (09) :3913-3919
[9]  
STILES AB, CATALYST SUPPORTS SU, P87
[10]   Surface oxides on supported Rh particles:: thermal decomposition of Rh oxide under high vacuum conditions [J].
Suhonen, S ;
Polvinen, R ;
Valden, M ;
Kallinen, K ;
Härkönen, M .
APPLIED SURFACE SCIENCE, 2002, 200 (1-4) :48-54