Interfacial enhancement of carbon fiber composites by growing TiO2 nanowires onto amine-based functionalized carbon fiber surface in supercritical water

被引：172

作者：

Ma, Lichun ^{[1
]}

Li, Nan ^{[2
]}

Wu, Guangshun ^{[3
]}

Song, Guojun ^{[1
]}

Li, Xiaoru ^{[1
]}

Han, Ping ^{[1
]}

Wang, Gang ^{[1
]}

Huang, Yudong ^{[4
]}

机构：

[1] Qingdao Univ, Inst Polymer Mat, Qingdao 266071, Peoples R China

[2] Dalian Univ Technol, Sch Chem Engn, Dept Polymer Sci & Mat, State Key Lab Fine Chem, Dalian 116024, Peoples R China

[3] Ludong Univ, Sch Chem & Mat Sci, Yantai 264025, Peoples R China

[4] Harbin Inst Technol, Sch Chem & Chem Engn, Harbin 150040, Heilongjiang, Peoples R China

来源：

APPLIED SURFACE SCIENCE | 2018年 / 433卷

基金：

美国国家科学基金会;

关键词：

Carbon fiber; Polymer-matrix composites (PMCs); Interface; Mechanical properties; Nanowires; UNSATURATED POLYESTER COMPOSITES; REINFORCED EPOXY COMPOSITES; MECHANICAL-PROPERTIES; GRAPHENE OXIDE; ZNO NANOWIRE; STRENGTH; TENSILE; TOUGHNESS; MELAMINE; GROWTH;

D O I：

10.1016/j.apsusc.2017.10.036

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel amine-based functionalization method was developed to improve the interfacial adhesion between TiO2 NWs and CFs in supercritical water. The microstructure, morphology and mechanical properties of CFs were investigated. It was found that introducing hexamethylenetetramine (HMTA) dendrimers and branched polyethyleneimine (PEI) on CF could increase significantly the adhesion strength between CF and TiO2 NWs and their interfacial shear strength with epoxy resin, and the order is CF-PEI-TiO2 NWs > CF-HMTA-TiO2 NWs > CF-COOH-TiO2 NWs > CF-TiO2 NW. Meanwhile, the reinforcing mechanisms and interfacial failure modes have also been discussed. We believe that these effective methods may provide theoretical foundation for the preparation of high performance composite materials. (C) 2017 Published by Elsevier B.V.

引用

页码：560 / 567

页数：8

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