Combustion Characteristics and Mechanism of Boron-based, Fuel-rich Propellants with Agglomerated Boron Powder

In order to extend the burning rate of boron-based, fuel-rich solid propellants with agglomerated boron powder, the effects of the boron content, the AP content, and of the magnesium powder content, on the burning rate and pressure exponent have been studied systematically. It has been shown that when the AP content is constant, the burning rate of the propellants increases with an increase in the agglomerated boron content. Furthermore, the burning rate and pressure exponent increase with increasing the contents of AP and magnesium powder. By means of single colour frame amplification photography and combustion wave tests, the combustion mechanism of these propellants has been investigated. It has been shown that the flame of the propellants becomes brighter by increasing the AP content, the dT/dx(cp) and dT/dx(gp) of the propellant FR-5 being around 6815 and 5789 degrees C/mm respectively, higher than those of FR-4, resulting in greater burning rates. The T-s of these propellants is above 683 degrees C, which is higher than the decomposition peak temperatures of agglomerated boron powder and of propellants (about 649 degrees C), which indicates that agglomerated boron powder is partially oxidized on the combustion surface, and the heat released from it may be beneficial to the combustion of the propellants.