共 47 条
MOF-templated nitrogen-doped porous carbon materials as efficient electrocatalysts for oxygen reduction reactions
被引:23
作者:

Wang, Suhong
论文数: 0 引用数: 0
h-index: 0
机构:
Liaoning Univ, Coll Chem, Shenyang 110036, Peoples R China Liaoning Univ, Coll Chem, Shenyang 110036, Peoples R China

Liu, Lin
论文数: 0 引用数: 0
h-index: 0
机构:
Liaoning Univ, Coll Chem, Shenyang 110036, Peoples R China Liaoning Univ, Coll Chem, Shenyang 110036, Peoples R China

Wang, Shi-Ming
论文数: 0 引用数: 0
h-index: 0
机构:
Liaoning Univ, Coll Light Ind, Shenyang 110036, Peoples R China Liaoning Univ, Coll Chem, Shenyang 110036, Peoples R China

Han, Zhengbo
论文数: 0 引用数: 0
h-index: 0
机构:
Liaoning Univ, Coll Chem, Shenyang 110036, Peoples R China Liaoning Univ, Coll Chem, Shenyang 110036, Peoples R China
机构:
[1] Liaoning Univ, Coll Chem, Shenyang 110036, Peoples R China
[2] Liaoning Univ, Coll Light Ind, Shenyang 110036, Peoples R China
来源:
INORGANIC CHEMISTRY FRONTIERS
|
2017年
/
4卷
/
07期
基金:
中国国家自然科学基金;
关键词:
METAL-FREE ELECTROCATALYSTS;
ORGANIC-FRAMEWORK;
HIGHLY EFFICIENT;
SCALABLE PREPARATION;
MESOPOROUS CARBONS;
SUPPORTED PLATINUM;
FUEL-CELLS;
GRAPHENE;
PERFORMANCE;
NANOTUBES;
D O I:
10.1039/c7qi00233e
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
MOF-templated nitrogen-doped porous carbon materials (NPCs) have been prepared by employing the previously reported MOF, [(CH3)(2)NH2](6)[Ni(H2O)(6)](3){Ni-6(eta(6)-TATAT)(4)(H2O)(12)}, as a precursor, which can act as efficient electrocatalysts for oxygen reduction reactions (ORRs). The carbonized MOF acts as the carbon source, and urea is employed as an additional nitrogen source. The urea modified carbon materials, carbonized at 800 degrees C, 900 degrees C and 1000 degrees C under Ar atmosphere, all show electrocatalytic activity for ORRs; the material carbonized at 900 degrees C exhibits a more appropriate nitrogen content, robust pore structure and an excellent degree of graphitization. In alkaline media, NPC-900 exhibits superior catalytic activity (the onset and half-wave potentials are -0.06 V and -0.23 V vs. Ag/AgCl, respectively), excellent long-term durability and outstanding methanol tolerance compared with the commercial Pt/C catalyst.
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收藏
页码:1231 / 1237
页数:7
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