Estimation of Kinetic Parameters for the Catalytic Oxidation of Substituted Phenols in Liquid-phase

被引：0

作者：

Cozma, Danut-Gabriel ^{[1
]}

Pui, Aurel ^{[1
]}

Ricoux, Remy ^{[2
]}

Mahy, Jean-Pierre ^{[2
]}

机构：

[1] Alexandru Ioan Cuza Univ, Fac Chem, Iasi 700506, Romania

[2] Univ Paris 11, Inst Mol Chem & Mat, Lab Bioorgan & Bioinorgan Chem, F-91405 Orsay, France

来源：

REVISTA DE CHIMIE | 2011年 / 62卷 / 01期

关键词：

kinetic parameters; statistical methods; oxidation reactions; ARTIFICIAL METALLOPROTEINS; COMPLEXES; EPOXIDATION; DESIGN;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cobalt (II) Schiff bases complexes were used as catalysts in an oxidation reaction of substituted phenol with molecular oxygen. The kinetics parameters (reaction order, rate constants) were calculated from the van't Hoff relation and their variation limits have been subsequently statistically estimated. The dependence of the oxidation reaction rate is evaluated according to the nature of the Schiff base used as a catalyst, using statistical and probabilistic methods.

引用

页码：82 / 88

页数：7

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