Efficient synthesis of (±)-7-isopropyl-2,10-dimethyl-8(E),10-undecadien-4-one and 3,7-dimethyl-11-oxo-2(E),6(E)-dodecadienol (oxocrinol) under ultrasound

被引：4

作者：

Kad, GL ^{[1
]}

Singh, V ^{[1
]}

Chaudhary, S ^{[1
]}

Setia, S ^{[1
]}

Bhandari, M ^{[1
]}

Singh, J ^{[1
]}

机构：

[1] Panjab Univ, Dept Chem, Chandigarh 160014, India

来源：

ULTRASONICS SONOCHEMISTRY | 2001年 / 8卷 / 02期

关键词：

ultrasound; (+/-)-7-isopropyl-2,10-dimethyl-8(E),10-undecadien-4-one; 3,7-dimethyl-11-oxo-2(E),6(E)-dodecadienol (oxocrinol); synthesis; terpenoid;

D O I：

10.1016/S1350-4177(00)00063-8

中图分类号：

O42 [声学];

学科分类号：

070206 ; 082403 ;

摘要：

A simple and convergent synthesis of the title compounds has been achieved involving Zn-Cu couple catalysed conjugate addition of allylic halides to alpha,beta -unsaturated carbonyl compounds promoted by ultrasonic waves in aqueous medium as a key step in good overall yields. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：123 / 126

页数：4

共 12 条

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