A new intramolecular migration of the imino group of O-arylketoximes to the aryl group under the Beckmann condition

被引：23

作者：

Kikugawa, Y ^{[1
]}

Tsuji, C ^{[1
]}

Miyazawa, E ^{[1
]}

Sakamoto, T ^{[1
]}

机构：

[1] Josai Univ, Fac Pharmaceut Sci, Sakado, Saitama 3500295, Japan

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 12期

关键词：

O-aryloxime; ZrCl4; electron-deficient nitrogen; Beckmann condition;

D O I：

10.1016/S0040-4039(01)00181-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

ZrCl4-mediated decomposition of O-arylketoximes in benzene leads to regioselective intramolecular migration of the imino group from the oxygen to the ortho position of the aryl group via electron-deficient nitrogen intermediates. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：2337 / 2339

页数：3

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