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One-component epoxy resin with imine as water-initiated latent hardener: Improvement of the mechanical and adhesive properties by the addition of methacrylate copolymer
被引:12
|作者:
Suzuki, K
Sugita, Y
Sanda, F
Endo, T
[1
]
机构:
[1] Konishi Co, Tsurumi Ku, Osaka 5380053, Japan
[2] Kyoto Univ, Grad Sch Engn, Dept Polymer Chem, Kyoto 6158510, Japan
[3] Yamagata Univ, Fac Engn, Dept Polymer Sci & Engn, Yonezawa, Yamagata 9928510, Japan
关键词:
imines;
one-component epoxy resin;
initiators adhesives;
mechanical properties;
D O I:
10.1002/app.21651
中图分类号:
O63 [高分子化学(高聚物)];
学科分类号:
070305 ;
080501 ;
081704 ;
摘要:
The effect of addition of methacrylate polymer into a one-component epoxy resin, containing Epikote 828 and diimine as a water-initiated hardener, was examined. Although the cured epoxy resin in the presence of methyl methacrylate-butyl acrylate (MMA-BA) copolymer was very brittle, the resin containing MMA-BA-[gamma-(methacryloxy)propyl]trimethoxysilane (TMSMA) copolymer showed good mechanical and adhesive properties. The adhesive strength of the cured epoxy resin containing MMABA-TMSMA copolymer was much higher than that without its polymer. (c) 2005 Wiley Periodicals, Inc.
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页码:1943 / 1949
页数:7
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